Radioactive iodine capture and storage from water using magnetite nanoparticles encapsulated in polypyrrole

Abstract

The effective capture and storage of radioactive iodine is of importance for nuclear waste storage during nuclear power station accidents. Here we report Fe3O4@PPy powder containing similar to 12 nm magnetite (Fe3O4) nanoparticles encapsulated in the polypyrrole (PPy) matrix. It shows 1627 mg/g uptake of iodine dissolved in water, within 2 h at room temperature. Fe3O4@PPy is ferromagnetic in nature and can be separated from water using external magnetic field. The nitrogen gas sweeping test at 30 degrees C shows release of 2% iodine from iodine adsorbed Fe3O4@PPy, revealing stable storage of iodine for a moderate period. The iodine-adsorbed magnetic powder can be regenerated by washing with ethanol. The XPS spectrum of iodine adsorbed Fe3O4@PPy confirmed the presence of polyiodides (I-3(-) and I-5(-)) bound to the PPy surface. This excellent iodine capture and storage from iodine contaminated water is an environment friendly, inexpensive and large scale method.