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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 13170 | - |
dc.citation.number | 39 | - |
dc.citation.startPage | 13166 | - |
dc.citation.title | DALTON TRANSACTIONS | - |
dc.citation.volume | 46 | - |
dc.contributor.author | Derrick, Jeffrey S | - |
dc.contributor.author | Kim, Yujeong | - |
dc.contributor.author | Tak, Hyeonwoo | - |
dc.contributor.author | Park, Kiyoung | - |
dc.contributor.author | Cho, Jaeheung | - |
dc.contributor.author | Kim, Sun Hee | - |
dc.contributor.author | Lim, Mi Hee | - |
dc.date.accessioned | 2023-12-21T21:41:52Z | - |
dc.date.available | 2023-12-21T21:41:52Z | - |
dc.date.created | 2017-10-13 | - |
dc.date.issued | 2017-10 | - |
dc.description.abstract | Metal(TMC) complexes (TMC = tetramethylcyclam) exclusively form trans-I diastereoisomers; thus, little is known about the trans-III isomers. Herein, we report a new method to prepare the trans-III-[Cu(TMC)]2+ complex via an anion effect. Our crystallographic, spectroscopic, and computational analyses validated that [Cu(TMC)](NO3)2 produced the trans-III complex, different from the trans-I structure of [Cu(TMC)](ClO4)2. | - |
dc.identifier.bibliographicCitation | DALTON TRANSACTIONS, v.46, no.39, pp.13166 - 13170 | - |
dc.identifier.doi | 10.1039/C7DT01489A | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.scopusid | 2-s2.0-85031032726 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/22802 | - |
dc.identifier.url | http://pubs.rsc.org/en/content/articlelanding/2017/dt/c7dt01489a#!divAbstract | - |
dc.identifier.wosid | 000412765000002 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Stereochemistry of metal tetramethylcyclam complexes directed by an unexpected anion effect | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | CYCLAM LIGANDS | - |
dc.subject.keywordPlus | COORDINATING SOLVENTS | - |
dc.subject.keywordPlus | NICKEL(II) COMPLEXES | - |
dc.subject.keywordPlus | OXOIRON(IV) COMPLEX | - |
dc.subject.keywordPlus | ELECTRON-TRANSFER | - |
dc.subject.keywordPlus | AMINE COMPLEXES | - |
dc.subject.keywordPlus | PERCHLORATE | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | 1,4,8,11-TETRAMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE | - |
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