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Cho, Jaeheung
BIOCC at UNIST
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dc.citation.endPage 13170 -
dc.citation.number 39 -
dc.citation.startPage 13166 -
dc.citation.title DALTON TRANSACTIONS -
dc.citation.volume 46 -
dc.contributor.author Derrick, Jeffrey S -
dc.contributor.author Kim, Yujeong -
dc.contributor.author Tak, Hyeonwoo -
dc.contributor.author Park, Kiyoung -
dc.contributor.author Cho, Jaeheung -
dc.contributor.author Kim, Sun Hee -
dc.contributor.author Lim, Mi Hee -
dc.date.accessioned 2023-12-21T21:41:52Z -
dc.date.available 2023-12-21T21:41:52Z -
dc.date.created 2017-10-13 -
dc.date.issued 2017-10 -
dc.description.abstract Metal(TMC) complexes (TMC = tetramethylcyclam) exclusively form trans-I diastereoisomers; thus, little is known about the trans-III isomers. Herein, we report a new method to prepare the trans-III-[Cu(TMC)]2+ complex via an anion effect. Our crystallographic, spectroscopic, and computational analyses validated that [Cu(TMC)](NO3)2 produced the trans-III complex, different from the trans-I structure of [Cu(TMC)](ClO4)2. -
dc.identifier.bibliographicCitation DALTON TRANSACTIONS, v.46, no.39, pp.13166 - 13170 -
dc.identifier.doi 10.1039/C7DT01489A -
dc.identifier.issn 1477-9226 -
dc.identifier.scopusid 2-s2.0-85031032726 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/22802 -
dc.identifier.url http://pubs.rsc.org/en/content/articlelanding/2017/dt/c7dt01489a#!divAbstract -
dc.identifier.wosid 000412765000002 -
dc.language 영어 -
dc.publisher ROYAL SOC CHEMISTRY -
dc.title Stereochemistry of metal tetramethylcyclam complexes directed by an unexpected anion effect -
dc.type Article -
dc.description.isOpenAccess FALSE -
dc.relation.journalWebOfScienceCategory Chemistry, Inorganic & Nuclear -
dc.relation.journalResearchArea Chemistry -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -
dc.subject.keywordPlus CRYSTAL-STRUCTURE -
dc.subject.keywordPlus CYCLAM LIGANDS -
dc.subject.keywordPlus COORDINATING SOLVENTS -
dc.subject.keywordPlus NICKEL(II) COMPLEXES -
dc.subject.keywordPlus OXOIRON(IV) COMPLEX -
dc.subject.keywordPlus ELECTRON-TRANSFER -
dc.subject.keywordPlus AMINE COMPLEXES -
dc.subject.keywordPlus PERCHLORATE -
dc.subject.keywordPlus REACTIVITY -
dc.subject.keywordPlus 1,4,8,11-TETRAMETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE -

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