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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 4642 | - |
dc.citation.number | 28 | - |
dc.citation.startPage | 4638 | - |
dc.citation.title | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | - |
dc.citation.volume | 2015 | - |
dc.contributor.author | Schilter, David | - |
dc.contributor.author | Fuller, Amy L. | - |
dc.contributor.author | Gray, Danielle L. | - |
dc.date.accessioned | 2023-12-22T00:38:46Z | - |
dc.date.available | 2023-12-22T00:38:46Z | - |
dc.date.created | 2017-09-13 | - |
dc.date.issued | 2015-10 | - |
dc.description.abstract | The heterobimetallic complexes [(dppe)Ni(pdt)Mo(CO)(4)], [(dcpe)Ni(pdt)Mo(CO)(4)], [(dppe)Ni(pdt)W(CO)(4)] and [(dcpe)Ni(pdt)W(CO)(4)] {dppe = Ph2P(CH2)(2)PPh2; dcpe = Cy2P(CH2)(2)PCy2; pdt(2-) = S-(CH2)(3)S-} have been prepared and structurally characterized. The internuclear separation in these (NiM0)-M-II species is highly sensitive to diphosphine basicity and is smallest in the dppe complexes wherein the planar Ni centres are electron-poor and require interaction with the group 6 metal. The (NiW0)-W-II species [(dppe)Ni(pdt)W(CO)(4)] was converted into its stable conjugate acid [(dppe)Ni(pdt)HW(CO)(4)](+), a rare example of a nickel-tungsten hydride. This (NiHWII)-H-II complex is an electrocatalyst for H+ reduction and is relevant to both biological and synthetic H-2-processing catalysts. | - |
dc.identifier.bibliographicCitation | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, v.2015, no.28, pp.4638 - 4642 | - |
dc.identifier.doi | 10.1002/ejic.201500740 | - |
dc.identifier.issn | 1434-1948 | - |
dc.identifier.scopusid | 2-s2.0-84943819192 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/22684 | - |
dc.identifier.url | http://onlinelibrary.wiley.com/doi/10.1002/ejic.201500740/abstract | - |
dc.identifier.wosid | 000362824100003 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Nickel-Molybdenum and Nickel-Tungsten Dithiolates: Hybrid Models for Hydrogenases and Hydrodesulfurization | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | Hydrogenases | - |
dc.subject.keywordAuthor | Hydrodesulfurization | - |
dc.subject.keywordAuthor | Hydrides | - |
dc.subject.keywordAuthor | Heterometallic complexes | - |
dc.subject.keywordAuthor | Bioorganometallic chemistry | - |
dc.subject.keywordPlus | ACTIVE-SITE | - |
dc.subject.keywordPlus | IRON HYDROGENASES | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | H-2 | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | CATALYSTS | - |
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