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DC Field | Value | Language |
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dc.citation.number | 19 | - |
dc.citation.startPage | 1606317 | - |
dc.citation.title | ADVANCED MATERIALS | - |
dc.citation.volume | 29 | - |
dc.contributor.author | Seo, Jeong-Min | - |
dc.contributor.author | Tan, Loon-Seng | - |
dc.contributor.author | Baek, Jong-Beom | - |
dc.date.accessioned | 2023-12-21T22:16:35Z | - |
dc.date.available | 2023-12-21T22:16:35Z | - |
dc.date.created | 2017-03-10 | - |
dc.date.issued | 2017-05 | - |
dc.description.abstract | Popularly utilized oxidation media, via nitric acid/sulfuric acid mixtures, are too corrosive and oxidizing to preserve structural integrity of highly ordered graphitic materials (carbon nanotubes (CNTs) and graphene). Here, for the most commonly used oxidation method, the important advantages of defect/edge-selective functionalization of carbon materials (CNTs/graphene/graphite) in a polyphosphoric acid (PPA)/phosphorous pentoxide (P2O5) medium are elucidated. The optimized PPA/P2O5 medium is a mild acid that is not only less corrosive than popularly utilized oxidation media, but also has a strong capability to drive Friedel-Crafts acylation by covalently modifying carbon materials. With a broader spectrum of functional groups accessible, the PPA/P2O5-driven Friedel-Crafts acylation offers more options for tailoring the properties and processing of carbon materials. | - |
dc.identifier.bibliographicCitation | ADVANCED MATERIALS, v.29, no.19, pp.1606317 | - |
dc.identifier.doi | 10.1002/adma.201606317 | - |
dc.identifier.issn | 0935-9648 | - |
dc.identifier.scopusid | 2-s2.0-85013483785 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/22160 | - |
dc.identifier.url | http://onlinelibrary.wiley.com/doi/10.1002/adma.201606317/abstract | - |
dc.identifier.wosid | 000401170600020 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Defect/Edge-Selective Functionalization of Carbon Materials by Direct Friedel-Crafts Acylation Reaction | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary; Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter | - |
dc.relation.journalResearchArea | Chemistry; Science & Technology - Other Topics; Materials Science; Physics | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | carbon nanotubes | - |
dc.subject.keywordAuthor | defect | - |
dc.subject.keywordAuthor | edge-selective functionalization | - |
dc.subject.keywordAuthor | Friedel-Crafts acylation | - |
dc.subject.keywordAuthor | graphene | - |
dc.subject.keywordAuthor | macromolecules | - |
dc.subject.keywordPlus | IN-SITU POLYMERIZATION | - |
dc.subject.keywordPlus | POLYPHOSPHORIC ACID | - |
dc.subject.keywordPlus | ELECTROCHEMICAL PROPERTIES | - |
dc.subject.keywordPlus | POLY(PHOSPHORIC ACID) | - |
dc.subject.keywordPlus | NANOTUBE MIXTURE | - |
dc.subject.keywordPlus | COMPOSITE FILMS | - |
dc.subject.keywordPlus | GRAPHENE | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | GRAPHITE | - |
dc.subject.keywordPlus | COVALENT | - |
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