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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 1052 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | 1046 | - |
dc.citation.title | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.citation.volume | 82 | - |
dc.contributor.author | Sultane, Prakash R. | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.date.accessioned | 2023-12-21T22:43:19Z | - |
dc.date.available | 2023-12-21T22:43:19Z | - |
dc.date.created | 2017-03-03 | - |
dc.date.issued | 2017-01 | - |
dc.description.abstract | The Burgess reagent ([methoxycarbonylsulfamoyl]triethylammonium hydroxide) has historically found utility as a dehydrating agent. Herein we show that, in the presence of dimethyl sulfoxide, the Burgess reagent efficiently and rapidly facilitates the oxidation of a broad range of primary and secondary alcohols to their corresponding aldehydes and ketones in excellent yields and under mild conditions, and can be combined with other transformations (e.g., Wittig olefinations). A mechanism similar to those described for the Pfitzner-Moffatt and Swern oxidations is proposed. | - |
dc.identifier.bibliographicCitation | JOURNAL OF ORGANIC CHEMISTRY, v.82, no.2, pp.1046 - 1052 | - |
dc.identifier.doi | 10.1021/acs.joc.6b02629 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.scopusid | 2-s2.0-85048361186 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/21518 | - |
dc.identifier.url | http://pubs.acs.org/doi/abs/10.1021/acs.joc.6b02629 | - |
dc.identifier.wosid | 000392569500022 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Burgess Reagent Facilitated Alcohol Oxidations in DMSO | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | STEREOSELECTIVE-SYNTHESIS | - |
dc.subject.keywordPlus | DIMETHYL-SULFOXIDE | - |
dc.subject.keywordPlus | INNER SALT | - |
dc.subject.keywordPlus | ALDEHYDES | - |
dc.subject.keywordPlus | AMIDES | - |
dc.subject.keywordPlus | GENERATION | - |
dc.subject.keywordPlus | NITRILES | - |
dc.subject.keywordPlus | KETONES | - |
dc.subject.keywordPlus | ESTERS | - |
dc.subject.keywordPlus | DERIVATIVES | - |
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