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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 11936 | - |
dc.citation.number | 15 | - |
dc.citation.startPage | 11933 | - |
dc.citation.title | RSC ADVANCES | - |
dc.citation.volume | 6 | - |
dc.contributor.author | Cheng, Tao | - |
dc.contributor.author | Chen, S | - |
dc.contributor.author | Lee, Kyu Cheol | - |
dc.contributor.author | Lee, Sang Myeon | - |
dc.contributor.author | Yang, Changduk | - |
dc.date.accessioned | 2023-12-22T00:12:40Z | - |
dc.date.available | 2023-12-22T00:12:40Z | - |
dc.date.created | 2016-12-07 | - |
dc.date.issued | 2016-01 | - |
dc.description.abstract | To enable a superior σ*-π* conjugation, we present a dithienodisilacyclohexadiene (DTS) analogue of DTS(FBTTh2)2 - namely, DTDS(FBTTh2)2 - by replacing dithienosilole (DTS) with a dithienodisilacyclohexadiene (DTDS) ring in the main backbone, where DTDS possesses a double silicon-bridged bithiophene (Si-Si). With this replacement, a blue shift of the absorption and a high-lying LUMO are observed. Disclosed herein is a structural change of DTDS(FBTTh2)2 (DTDS to ox-DTDS skeleton as the corresponding oxidation structure) occurring under ambient conditions, which is monitored by real-time 1H NMR and UV absorption methods. This work not only provides a full understanding of the nature of DTDS, but also uses unique DTDS chemistry as a new toolbox to develop systems as novel functionality materials. | - |
dc.identifier.bibliographicCitation | RSC ADVANCES, v.6, no.15, pp.11933 - 11936 | - |
dc.identifier.doi | 10.1039/C5RA23514F | - |
dc.identifier.issn | 2046-2069 | - |
dc.identifier.scopusid | 2-s2.0-84957098622 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/20902 | - |
dc.identifier.url | http://pubs.rsc.org/en/content/articlelanding/2016/ra/c5ra23514f#!divAbstract | - |
dc.identifier.wosid | 000369545800002 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | A dithienodisilacyclohexadiene (DTDS)-based conjugated model semiconductor: understanding unique features and monitoring structural transition | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | ORGANIC SOLAR-CELLS | - |
dc.subject.keywordPlus | COPOLYMERS | - |
dc.subject.keywordPlus | MOLECULES | - |
dc.subject.keywordPlus | POLYMER | - |
dc.subject.keywordPlus | DESIGN | - |
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