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김용환

Kim, Yong Hwan
Enzyme and Protein Engineering Lab.
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Enzymatic photosynthesis of formate from carbon dioxide coupled with highly efficient photoelectrochemical regeneration of nicotinamide cofactors

Author(s)
Nam, Dong HeonKuk, Su KeunChoe, HyunjunLee, SumiKo, Jong WanSon, Eun JinChoi, Eun-GyuKim, Yong HwanPark, Chan Beum
Issued Date
2016-11
DOI
10.1039/C6GC02110G
URI
https://scholarworks.unist.ac.kr/handle/201301/20774
Fulltext
http://pubs.rsc.org/en/Content/ArticleLanding/2016/GC/C6GC02110G
Citation
GREEN CHEMISTRY, v.18, no.22, pp.5989 - 5993
Abstract
We present the photoelectrochemical (PEC) regeneration of nicotinamide cofactors (NADH) coupled with the enzymatic synthesis of formate from CO2 towards mimicking natural photosynthesis. The water oxidation-driven PEC platform exhibited high yield and the rate of NADH regeneration was compared to many other homogeneous, photochemical systems. We successfully coupled solar-assisted NADH reduction with enzymatic CO2 reduction to formate under continuous CO2 injection.
Publisher
ROYAL SOC CHEMISTRY
ISSN
1463-9262
Keyword
BIOCATALYZED ARTIFICIAL PHOTOSYNTHESISSOLUBLE ZINC PORPHYRINVISIBLE-LIGHTUNCOMPENSATED RESISTANCECO2 REDUCTIONFORMIC-ACIDWATERDEHYDROGENASEPHOTOREDUCTIONCONVERSION

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