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Kim, Jin Young
Next Generation Energy Laboratory
Research Interests
  • Polymer solar cells, QD solar cells, organic-inorganic hybrid solar cells, perovskite solar cells, OLEDs, PeLEDs, organic FETs

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Dithieno[2,3-d:2',3'-d']benzo[1,2-b:4,5-b']dithiophene (DTBDAT)-based copolymers for high-performance organic solar cells

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Title
Dithieno[2,3-d:2',3'-d']benzo[1,2-b:4,5-b']dithiophene (DTBDAT)-based copolymers for high-performance organic solar cells
Author
Lee, Ye SeulSong, SeyeongYoon, Yung JinLee, Yun-JiKwon, Soon-KiKim, Jin YoungKim, Yun-Hi
Issue Date
2016-10
Publisher
WILEY-BLACKWELL
Citation
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, v.54, no.19, pp.3182 - 3192
Abstract
P(BDT-TCNT) and P(DTBDAT-TCNT), which has an extended conjugation length, were designed and synthesized for applications in organic solar cell (OSCs). The solution absorption maxima of P(DTBDAT-TCNT) with the extended conjugation were red-shifted by 5-15 nm compared with those of P(BDT-TCNT). The optical band gaps and highest occupied molecular orbital (HOMO) energy levels of both P(BDT-TCNT) and P(DTBDAT-TCNT) were similar. The structure properties of thin films of these materials were characterized using grazing-incidence wide-angle X-ray scattering and tapping-mode atomic force microscopy, and charge carrier mobilities were characterized using the space-charge limited current method. OSCs were formed using [6,6]-phenyl-C-71-butyric acid methyl ester (PC71BM) as the electron acceptor and 3% diphenylether as additive suppress aggregation. OSCs with P(BDT-TCNT) as the electron donor exhibited a power conversion efficiency (PCE) of 4.10% with a short-circuit current density of J(SC)=9.06 mA/cm(2), an open-circuit voltage of V-OC=0.77 V, and a fill factor of FF=0.58. OSCs formed using P(DTBDAT-TCNT) as the electron donor layer exhibited a PCE of 5.83% with J(SC)=12.2 mA/cm(2), V-OC=0.77 V, and FF=0.62.
URI
https://scholarworks.unist.ac.kr/handle/201301/20753
URL
http://onlinelibrary.wiley.com/doi/10.1002/pola.28205/abstract
DOI
10.1002/pola.28205
ISSN
0887-624X
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