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DC Field | Value | Language |
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dc.citation.endPage | 121 | - |
dc.citation.startPage | 111 | - |
dc.citation.title | JOURNAL OF MEMBRANE SCIENCE | - |
dc.citation.volume | 523 | - |
dc.contributor.author | Nguyen, Thi Phuong Nga | - |
dc.contributor.author | Jun, Byung-Moon | - |
dc.contributor.author | Kwon, Young-Nam | - |
dc.date.accessioned | 2023-12-21T22:41:37Z | - |
dc.date.available | 2023-12-21T22:41:37Z | - |
dc.date.created | 2016-10-28 | - |
dc.date.issued | 2017-02 | - |
dc.description.abstract | This study investigates the change in performance and properties of various forward osmosis (FO) membranes resulting from exposure to chlorine by conducting performance test and characterization using ATR-FTIR, XPS, zeta potential, NMR and, particularly, ToF-SIMS analyses. The data obtained through the ToF-SIMS measurements suggested that chlorine first reacted with the acetyl/acetate group of the cellulose triacetate (CTA)-based membrane and then with the pyranose ring. Chlorine bound to the membrane surface weakened the H-bond of the CTA-based membrane, resulting in an increase in water flux and reverse salt flux (RSF) as the chlorine exposure time or chlorine concentration increased. A high chlorine dosage cleaved the pyranose ring, leading to loss of membrane selectivity. After chlorination with a high chlorine dosage, the structure of the CTA-based membrane eventually presented fatigue upon an increase in filtration time, and the oxidation of the CTA-based membrane due to exposure to chlorine was maximal at pH 7. The polyamide (PA)-based FO membrane was more sensitive to chlorine under acidic conditions, resulting in a greater loss of selectivity than that of the CTA-based FO membrane. However, an alkaline chlorine solution insignificantly affected both the CTA-based and TFC-based FO membranes. This study shows that the TFC PA-based FO membrane yields a high water flux, but its chlorine tolerance must be improved to be practically applicable in various fields. | - |
dc.identifier.bibliographicCitation | JOURNAL OF MEMBRANE SCIENCE, v.523, pp.111 - 121 | - |
dc.identifier.doi | 10.1016/j.memsci.2016.09.020 | - |
dc.identifier.issn | 0376-7388 | - |
dc.identifier.scopusid | 2-s2.0-84990911214 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/20668 | - |
dc.identifier.url | http://www.sciencedirect.com/science/article/pii/S0376738816316234 | - |
dc.identifier.wosid | 000392772900012 | - |
dc.language | 영어 | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.title | The chlorination mechanism of integrally asymmetric cellulose triacetate (CTA)-based and thin film composite polyamide-based forward osmosis membrane | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical; Polymer Science | - |
dc.relation.journalResearchArea | Engineering; Polymer Science | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | Forward osmosis membrane | - |
dc.subject.keywordAuthor | Cellulose acetate | - |
dc.subject.keywordAuthor | Polyamide | - |
dc.subject.keywordAuthor | Chlorination | - |
dc.subject.keywordAuthor | ToF-SIMS | - |
dc.subject.keywordPlus | HYPOCHLORITE DEGRADATION | - |
dc.subject.keywordPlus | SODIUM-HYPOCHLORITE | - |
dc.subject.keywordPlus | PVDF MEMBRANE | - |
dc.subject.keywordPlus | ACETATE | - |
dc.subject.keywordPlus | RO | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | BEHAVIOR | - |
dc.subject.keywordPlus | IMPACT | - |
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