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Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)
  • Crystal Engineering
  • Supramolecular coordination chemistry

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Graphite oxide as an efficient and robust support for Pt nanoparticles in electrocatalytic methanol oxidation

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dc.contributor.author Prabakar, S.J. Richard ko
dc.contributor.author Kim, Yusin ko
dc.contributor.author Jeong, Jaehyang ko
dc.contributor.author Jeong, Seok ko
dc.contributor.author Lah, Myoung Soo ko
dc.contributor.author Pyo, Myoungho ko
dc.date.available 2015-12-29T06:28:58Z -
dc.date.created 2015-12-29 ko
dc.date.issued 2016-01 ko
dc.identifier.citation ELECTROCHIMICA ACTA, v.188, pp.472 - 479 ko
dc.identifier.issn 0013-4686 ko
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/18011 -
dc.description.abstract Pt nanoparticles were encapsulated in graphite oxide (GTO) and used as electrocatalysts for methanol oxidation. When compared with Pt nanoparticles composited with graphene oxide (GO/Pt), Pt nanoparticles sandwiched between the graphene layers of a GTO framework (GTO/Pt) showed significantly improved electrocatalytic performance and stability for methanol oxidation. The simultaneous reduction of Pt4+ and oxygen moieties of GTO during the synthesis of GTO/Pt resulted in a composite with moderately stacked graphene layers. This structure enhanced the kinetic feasibility of methanol oxidation with no decrease in the active surface area of Pt nanoparticles, and also increased the tolerance for the adsorption of surface-adsorbed intermediates. In addition, in contrast to the GO/Pt composite, the Pt nanoparticles in GTO/Pt did not aggregate during the electrochemical reaction, which was responsible for the superior long-term stability of the GTO/Pt. Thermal reduction of GTO/Pt (rGTO/Pt) resulted in rather inferior electrocatalytic responses due to a decrease in the accessible surface area of Pt nanoparticles in the densely stacked graphene layers. Therefore, other than a synthetic convenience (GTO does not require a mechanical exfoliation step.), this work suggests that the use of GTO rather than GO as a support could be a more efficient tactic in preparing graphene composites when the electrochemical reaction on the surface of impregnated nanoparticles is important. ko
dc.description.statementofresponsibility close -
dc.language 영어 ko
dc.publisher PERGAMON-ELSEVIER SCIENCE LTD ko
dc.title Graphite oxide as an efficient and robust support for Pt nanoparticles in electrocatalytic methanol oxidation ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-84949988808 ko
dc.identifier.wosid 000370986500054 ko
dc.type.rims ART ko
dc.description.wostc 0 *
dc.date.tcdate 2015-12-29 *
dc.identifier.doi 10.1016/j.electacta.2015.12.051 ko
dc.identifier.url http://www.sciencedirect.com/science/article/pii/S0013468615309695 ko
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