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Shin, Tae Joo
UNIST Synchrotron Radiation Research Laboratory
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  • Synchrotron Radiation Application Researches

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Two different mechanisms of CH3NH3PbI3 film formation in one-step deposition and its effect on photovoltaic properties of OPV-type perovskite solar cells

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dc.contributor.author Bae, Seunghwan ko
dc.contributor.author Han, Seung Jin ko
dc.contributor.author Shin, Tae Joo ko
dc.contributor.author Jo, Won Ho ko
dc.date.available 2015-12-10T02:40:25Z -
dc.date.created 2015-12-10 ko
dc.date.issued 2015-10 ko
dc.identifier.citation JOURNAL OF MATERIALS CHEMISTRY A, v.3, no.47, pp.23964 - 23972 ko
dc.identifier.issn 2050-7488 ko
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/17953 -
dc.description.abstract Although the one-step deposition method has intensively been studied because of the simple and easy fabrication of perovskite films, uncontrolled crystallization of perovskite during one-step deposition often results in films with small crystallites and low surface coverage, leading to low photovoltaic performance. In this study, we have proposed the optimum processing conditions to afford a favorable crystal morphology of perovskite films for achieving high power conversion efficiency of perovskite solar cells. Two different morphologies, tree-like and flower-like morphologies, are developed depending upon the spin-coating time and post-heat treatment temperature. When the perovskite is crystallized from the liquid film after a short spin-coating time, the flower-like morphology is developed, whereas the treelike morphology is developed when the perovskite is crystallized for a long spin-coating time. When the morphology evolution is monitored using in situ optical microscopy and X-ray diffraction to investigate the origin of the difference between tree-like and flower-like morphologies, it reveals that the CH3NH3I-PbI2-solvent complex is formed to develop the tree-like morphology before CH3NH3PbI3 crystals are formed, whereas the flower-like morphology is developed when the CH3NH3PbI3 crystals are formed directly from the liquid film without the formation of the CH3NH3I-PbI2-solvent complex. The film with a flower-like morphology, as prepared from DMSO solution, has large-sized crystallites, and the crystallites are highly orientated along (112) and (200) directions, resulting in a high PCE of 13.85%, whereas the film with a tree-like morphology has small-sized crystallites with random crystal orientation, exhibiting very low PCEs. ko
dc.description.statementofresponsibility close -
dc.language 영어 ko
dc.publisher ROYAL SOC CHEMISTRYROYAL SOC CHEMISTRY ko
dc.title Two different mechanisms of CH3NH3PbI3 film formation in one-step deposition and its effect on photovoltaic properties of OPV-type perovskite solar cells ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-84948443720 ko
dc.identifier.wosid 000365205000038 ko
dc.type.rims ART ko
dc.description.scopustc 0 *
dc.date.scptcdate 2015-12-10 *
dc.identifier.doi 10.1039/c5ta06870c ko
dc.identifier.url http://pubs.rsc.org/en/Content/ArticleLanding/2015/TA/C5TA06870C#!divAbstract ko
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