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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 1258 | - |
dc.citation.number | 11 | - |
dc.citation.startPage | 1254 | - |
dc.citation.title | ACS MACRO LETTERS | - |
dc.citation.volume | 4 | - |
dc.contributor.author | Todd, Alexander D. | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.date.accessioned | 2023-12-22T00:37:27Z | - |
dc.date.available | 2023-12-22T00:37:27Z | - |
dc.date.created | 2015-12-02 | - |
dc.date.issued | 2015-11 | - |
dc.description.abstract | Kumada catalyst-transfer polycondensation was used to synthesize poly(5,6-difluorobenzotriazole-alt-4-hexylthiophene) (PFBTzHT), an alternating donor-acceptor conjugated polymer, in a controlled manner. Through a series of kinetic studies, a linear relationship between the monomer conversion and the molecular weight of the resulting polymer was observed while maintaining narrow polydispersities (Ds ≤ 1.4). Moreover, the Mn displayed a linear relationship with the initial monomer-to-catalyst feed ratio, and polymers with Mns up to 25 kDa were successfully synthesized. All-conjugated block copolymers containing segments of PFBTzHT and poly(3-hexylthiophene) (P3HT) were also obtained in various compositions (30-70% P3HT) via sequential monomer addition in a single vessel. © 2015 American Chemical Society | - |
dc.identifier.bibliographicCitation | ACS MACRO LETTERS, v.4, no.11, pp.1254 - 1258 | - |
dc.identifier.doi | 10.1021/acsmacrolett.5b00505 | - |
dc.identifier.issn | 2161-1653 | - |
dc.identifier.scopusid | 2-s2.0-84947219361 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/17921 | - |
dc.identifier.url | http://pubs.acs.org/doi/10.1021/acsmacrolett.5b00505 | - |
dc.identifier.wosid | 000365147000014 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Controlled Synthesis of an Alternating Donor-Acceptor Conjugated Polymer via Kumada Catalyst-Transfer Polycondensation | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | CHAIN-GROWTH POLYMERIZATION | - |
dc.subject.keywordPlus | SOLAR-CELLS | - |
dc.subject.keywordPlus | COPOLYMERS | - |
dc.subject.keywordPlus | PHOTOVOLTAICS | - |
dc.subject.keywordPlus | EXCHANGE | - |
dc.subject.keywordPlus | ROUTE | - |
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