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DC Field | Value | Language |
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dc.citation.endPage | 3494 | - |
dc.citation.number | 21 | - |
dc.citation.startPage | 3488 | - |
dc.citation.title | CHEMCATCHEM | - |
dc.citation.volume | 7 | - |
dc.contributor.author | Park, Hunmin | - |
dc.contributor.author | Youn, Duck Hyun | - |
dc.contributor.author | Kim, Jae Young | - |
dc.contributor.author | Kim, Won Yong | - |
dc.contributor.author | Choi, Yo Han | - |
dc.contributor.author | Lee, Young Hye | - |
dc.contributor.author | Choi, Sun Hee | - |
dc.contributor.author | Lee, Jae Sung | - |
dc.date.accessioned | 2023-12-22T00:37:50Z | - |
dc.date.available | 2023-12-22T00:37:50Z | - |
dc.date.created | 2015-11-23 | - |
dc.date.issued | 2015-11 | - |
dc.description.abstract | The Fischer-Tropsch synthesis (FTS) is a feasible pathway to chemicals and fuels from underutilized resources like coal, natural gas, biomass, and shale gas, instead of the current petroleum-based production. Owing to its high activity and low price, the iron-based catalysts are widely used in FTS, yet catalysts with higher activity and better selectivity should be developed for widespread applications. Herein, we report a unique strategy to synthesize an efficient iron catalyst for FTS by applying a graphitic carbon nitride (g-C3N4) as a sacrificial support. The iron catalyst on g-C3N4 is effectively reduced to a state that is rapidly and selectively converted to highly crystalline and pure Hagg carbide (-Fe5C2) phase during the FTS reaction. The obtained catalyst exhibits outstanding CO conversion, and high selectivity for C5+ products, outperforming most of the recently reported carbon-based iron catalysts. | - |
dc.identifier.bibliographicCitation | CHEMCATCHEM, v.7, no.21, pp.3488 - 3494 | - |
dc.identifier.doi | 10.1002/cctc.201500794 | - |
dc.identifier.issn | 1867-3880 | - |
dc.identifier.scopusid | 2-s2.0-84946092184 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/17868 | - |
dc.identifier.url | http://onlinelibrary.wiley.com/doi/10.1002/cctc.201500794/abstract | - |
dc.identifier.wosid | 000364330600011 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Selective Formation of Hagg Iron Carbide with g-C3N4 as a Sacrificial Support for Highly Active Fischer-Tropsch Synthesis | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | carbon | - |
dc.subject.keywordAuthor | hydrocarbons | - |
dc.subject.keywordAuthor | iron | - |
dc.subject.keywordAuthor | nitrides | - |
dc.subject.keywordAuthor | supported catalysts | - |
dc.subject.keywordPlus | GRAPHITIC CARBON NITRIDE | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | NANOPARTICLES | - |
dc.subject.keywordPlus | NANOTUBES | - |
dc.subject.keywordPlus | NITROGEN | - |
dc.subject.keywordPlus | OXIDE | - |
dc.subject.keywordPlus | HYDROCARBONS | - |
dc.subject.keywordPlus | WATER | - |
dc.subject.keywordPlus | SIZE | - |
dc.subject.keywordPlus | GAS | - |
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