dc.citation.endPage |
691 |
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dc.citation.number |
5 |
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dc.citation.startPage |
685 |
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dc.citation.title |
POLYMER-KOREA |
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dc.citation.volume |
19 |
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dc.contributor.author |
Lee, SC |
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dc.contributor.author |
Park, Lee Soon |
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dc.date.accessioned |
2023-12-22T12:41:13Z |
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dc.date.available |
2023-12-22T12:41:13Z |
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dc.date.created |
2015-09-30 |
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dc.date.issued |
1995-09 |
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dc.description.abstract |
For the purpose of increasing molecular weight of poly (phenylene sulfide), PPS, copolymerization method and two-stage polymerization method were investigated. The thermal properties and molecular weight of copolymers and homopolymers were determined by DSC thermal analyzer and high temperature (210 degrees C) GPC with 1-chloronaphthalene as eluent, respectively. Copolymers were prepared by the reaction of Na2S . 9H(2)O (SS) with p-dichlorobenzene (p-DCB) and m-dichlorobenzene (m-DCB) or 1,2,4-trichlorobenzene (TCB) in N-methyl-2-pyrrolidinone (NMP) solvent at 250 degrees C. In case of the PPS copolymers synthesized by the reaction of m-DCB/p-DCB/SS, molecular weight, T-g's, and T-m's were lower than those of PPS homopolymer. On the other hand, the T-g's of copolymer synthesized by the reaction of TCB/p-DCB/SS increased with increasing amount of TCB comonomer and the use of minor amount (2 mole%) of TCB comonomer gave higher molecular weight polymer than PPS homopolymer. Two-stage polymerization of PPS reported Kureha company and a simplified direct two-stage polymerization were compared with one-stage polymerization of PPS with increased reaction time or m-DCB and TCB copolymerization. It was found that PPS homopolymer by the simplified two-stage polymerization method gave higher molecular weight PPS sample than those by the one-stage polymerization with increased reaction time or copolymerizations |
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dc.identifier.bibliographicCitation |
POLYMER-KOREA, v.19, no.5, pp.685 - 691 |
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dc.identifier.issn |
0379-153X |
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dc.identifier.uri |
https://scholarworks.unist.ac.kr/handle/201301/17282 |
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dc.identifier.url |
http://www.cheric.org/research/tech/periodicals/view.php?seq=7159 |
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dc.identifier.wosid |
A1995UH06700018 |
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dc.language |
한국어 |
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dc.publisher |
POLYMER SOC KOREA |
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dc.title |
Synthesis of PPS by copolymerization and two-stage polymerization and their thermal properties |
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dc.type |
Article |
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