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Synthesis and characterization of poly(N-arylcarbazole-alt-aniline) copolymers as blue-emitting host matrix for polymer light-emitting diodes

Author(s)
Wang, HuiRyu, Jeong-TakHan, Yoon SooKim, Dae-HwanChoi, Byeong DaePark, Lee SoonTeng, DayongKwon, Younghwan
Issued Date
2006
DOI
10.1080/15421400600930417
URI
https://scholarworks.unist.ac.kr/handle/201301/17147
Fulltext
http://www.tandfonline.com/doi/abs/10.1080/15421400600930417
Citation
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, v.459, pp.95 - 107
Abstract
Thermally stable and solution-processable poly(N-arylcarbazole-alt-aniline) copolymers with high structural integrity were synthesized in good yields via palladium-catalyzed polycondensation of aniline with corresponding N-arylcarbazole monomers such as N-(2-ethylhexyloxyphenyl)-3,6-dibromocarbazole, bis[6-bromo-N-(2-ethylhexyloxyphenyl)carbazole-3-yl] and N-(4-(2-ethylhexyl)-3,5-dibromomethylene-phenyl)carbazole, respectively. The optical and electrochemical properties of these copolymers were measured and compared with those of poly(N-alkylcarbazole-alt-aniline) copolymer. All synthesized poly(N-arylcarbazole-alt-aniline) copolymers showed maximum UV-Vis absorption peaks at around 300 nm in THF solution, and exhibited maximum photoluminescence peaks in the blue emission range from 430 to 460 nm. It was also found that poly(N-arylcarbazole-alt-aniline) copolymers had wider band gap energy than poly(N-alkylcarbazole-alt-aniline) copolymer
Publisher
TAYLOR & FRANCIS LTD
ISSN
1542-1406
Keyword (Author)
blue emissionhost matrixN-arylcarbazoletriarylamine
Keyword
NITROGEN-HETEROCYCLESPHOTOCONDUCTIVITYCARBAZOLECRYSTAL

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