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Yang, Changduk
Advanced Tech-Optoelectronic Materials Synthesis Lab (ATOMS)
Research Interests
  • Optoelectronic materials synthesis/organic electronics, functionalization of carbonaceous solids, advanced materials chemistry, macromolecular chemistry

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A Balanced Face-On to Edge-On Texture Ratio in Naphthalene Diimide-Based Polymers with Hybrid Siloxane Chains Directs Highly Efficient Electron Transport

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dc.contributor.author Kim, Yiho ko
dc.contributor.author Long, Dang Xuan ko
dc.contributor.author Lee, Junghoon ko
dc.contributor.author Kim, Gyoungsik ko
dc.contributor.author Shin, Tae Joo ko
dc.contributor.author Nam, Kyung-Wan ko
dc.contributor.author Noh, Yong-Young ko
dc.contributor.author Yang, Changduk ko
dc.date.available 2015-09-11T04:17:32Z -
dc.date.created 2015-09-11 ko
dc.date.issued 2015-08 ko
dc.identifier.citation MACROMOLECULES, v.48, no.15, pp.5179 - 5187 ko
dc.identifier.issn 0024-9297 ko
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/16793 -
dc.description.abstract Structure property relationships associated with a hybrid siloxane-terminated hexyl chain (SiC6), photophysics, molecular packing, thin-film morphology, and charge carrier transport are reported for two novel naphthalene diimide (NDI)-based polymers; P(NDI2SiC6-T2) consists of NDI and bithiophene (T2) repeating units, while for P(NDI2SiC6-TVT), the (E)-2-(2-(thiophen-2-yl)vinyl)thiophene (TVT) units are introduced into the NDI-based backbone. The analysis of the optical spectra shows that the preaggregation of these polymers in solution is highly sensitive to the choice of solvent such that the films prepared by using different solvents can be "tuned" with regard to their degrees and types of the aggregates. In-depth morphology investigations (atomic force microscopy (AFM), grazing incidence X-ray diffraction (GIXD), and near-edge X-ray absorption fine structure (NEXAFS)) combined with device optimization studies are used to probe the interplay between molecular structure, molecular packing, and OFET mobility. It is found that the polymer films cast as a coating from chloroform (CF) solvent favor a mixed face-on and edge-on orientation, while 1-chloronaphthalene (CN)-cast films favor an almost entirely edge-on orientation, resulting in a difference in mobility between CF- and CN-cast devices. Within this work, the annealed P(NDI2SiC6-T2) device fabricated from CF, despite showing a less densely packed organization, shows the highest electron mobility of up to 1.04 cm(2)/V. s due to a highly balanced face-on to edge-on ratio. This work, for the first time, advances our understanding for how the balanced face-on to edge-on ratio plays a dramatic role in facilitating charge transport, opening a new charge-transport mechanism in electronic devices ko
dc.description.statementofresponsibility close -
dc.language 영어 ko
dc.publisher AMER CHEMICAL SOC ko
dc.title A Balanced Face-On to Edge-On Texture Ratio in Naphthalene Diimide-Based Polymers with Hybrid Siloxane Chains Directs Highly Efficient Electron Transport ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-84939176867 ko
dc.identifier.wosid 000359500100014 ko
dc.type.rims ART ko
dc.description.wostc 0 *
dc.description.scopustc 0 *
dc.date.tcdate 2015-12-28 *
dc.date.scptcdate 2015-11-04 *
dc.date.scptcdate 2015-11-04 *
dc.identifier.doi 10.1021/acs.macromol.5b01012 ko
dc.identifier.url http://pubs.acs.org/doi/abs/10.1021/acs.macromol.5b01012 ko
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