The WO3/W/PbBi2Nb1.9Ti0.1O9 photocatalyst was fabricated by depositing the tungsten clusters over the p-type perovskite base material with the chemical vapor deposition method, and later partly oxidizing the surfaces of these clusters to obtain n-type WO3 overlayers and W metal layer as an Ohmic junction. This NCPC showed unprecedented high activity for the photocatalytic oxidation of water, photocurrent generation, and acetaldehyde decomposition under visible light irradiation (lambda >= 420 nm). (c) 2006 American Institute of Physics