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Lee, Jae Sung
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dc.citation.endPage 366 -
dc.citation.number 1 -
dc.citation.startPage 362 -
dc.citation.title JOURNAL OF PHYSICAL CHEMISTRY -
dc.citation.volume 96 -
dc.contributor.author Lee, Jae Sung -
dc.contributor.author LEE, Kyung Hee -
dc.contributor.author LEE, Jeong Yong -
dc.date.accessioned 2023-12-22T13:07:50Z -
dc.date.available 2023-12-22T13:07:50Z -
dc.date.created 2015-07-27 -
dc.date.issued 1992-01 -
dc.description.abstract In order to establish procedures to determine the number of exposed metal sites and the particle size of molybdenum carbide catalysts by selective chemisorption of CO and H-2, alumina supported molybdenum and its carbides were studied by CO and H-2 chemisorption at different temperatures, TPD, XRD, and TEM. Carbon monoxide appeared to chemisorb molecularly on molybdenum carbide at 196 K, yet substantial amounts of chemisorbed CO desorbed upon heating to room temperature. Hydrogen chemisorption was an activated process and required elevated temperatures. Hence, CO chemisorption at 196 K and H-2 chemisorption as the sample is cooled from 620 K to room temperature provided the number of exposed metal sites and the particle sizes, which are consistent with each other and with TEM results as well -
dc.identifier.bibliographicCitation JOURNAL OF PHYSICAL CHEMISTRY, v.96, no.1, pp.362 - 366 -
dc.identifier.doi 10.1021/j100180a067 -
dc.identifier.issn 0022-3654 -
dc.identifier.scopusid 2-s2.0-27844520033 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/13027 -
dc.identifier.url http://pubs.acs.org/doi/abs/10.1021/j100180a067 -
dc.identifier.wosid A1992GZ69700067 -
dc.language 영어 -
dc.publisher American Chemical Society -
dc.title.alternative SELECTIVE CHEMISORPTION OF CARBON-MONOXIDE AND HYDROGEN OVER SUPPORTED MOLYBDENUM CARBIDE CATALYSTS -
dc.title SELECTIVE CHEMISORPTION OF CARBON-MONOXIDE AND HYDROGEN OVER SUPPORTED MOLYBDENUM CARBIDE CATALYSTS -
dc.type Article -
dc.description.journalRegisteredClass scopus -

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