ScholarWorks: Thermal and chemical stability of titanium-substituted MCM-41

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Lee, Jae Sung

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Photocatalytic water splitting, artificial photosynthesis, fuel cells, heterogeneous catalysis

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Thermal and chemical stability of titanium-substituted MCM-41

DC Field	Value	Language
dc.contributor.author	Rhee, Chang Houn	ko
dc.contributor.author	Lee, Jae Sung	ko
dc.date.available	2015-07-29T00:57:35Z	-
dc.date.created	2015-07-28	ko
dc.date.issued	1996-08	-
dc.identifier.citation	CATALYSIS LETTERS, v.40, no.3-4, pp.261 - 264	ko
dc.identifier.issn	1011-372X	ko
dc.identifier.uri	https://scholarworks.unist.ac.kr/handle/201301/12953	-
dc.identifier.uri	http://link.springer.com/article/10.1007%2FBF00815293	ko
dc.description.abstract	The thermal and chemical stability of a titanium-substituted MCM41 (TiMCM-41) with Si/Ti mole ratio of 39 and pore diameter of 2.4 nm was studied with the small-angle X-ray diffraction and X-ray absorption near-edge structure techniques. The TiMCM-41 was stable in helium flow below 1273 K and under gas-phase reaction conditions of ethanol dehydrogenation (ethanol/O-2 = 1 mol/mol, 373-723 K). Under liquid-phase reaction conditions of phenol hydroxylation (phenol/35% H2O2/acetone in moles = 3 : 1 :7, 333 K), however, it lost the MCM-41 structure and titanium was leached out of the silicalite framework	ko
dc.description.statementofresponsibility	close	-
dc.language	ENG	ko
dc.publisher	SPRINGER	ko
dc.subject	Ti-substituted MCM-41	ko
dc.subject	stability	ko
dc.subject	dehydrogenation of ethanol	ko
dc.subject	hydroxylation of phenol	ko
dc.subject	XRD	ko
dc.subject	XANES	ko
dc.title	Thermal and chemical stability of titanium-substituted MCM-41	ko
dc.title.alternative	Thermal and chemical stability of titanium-substituted MCM-41	ko
dc.type	ARTICLE	ko
dc.identifier.scopusid	2-s2.0-0000792952	ko
dc.identifier.wosid	A1996VE92300022	ko
dc.type.rims	ART	ko
dc.description.wostc	39	*
dc.description.scopustc	35	*
dc.date.tcdate	2015-12-28	*
dc.date.scptcdate	2015-11-04	*
dc.identifier.doi	10.1007/BF00815293	ko