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Lee, Jae Sung
Eco-friendly Catalysis and Energy Lab
Research Interests
  • Photocatalytic water splitting, artificial photosynthesis, fuel cells, heterogeneous catalysis

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Molybdenum nitride and carbide prepared from heteropolyacid II. Hydrodenitrogenation of indole

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dc.contributor.author Li, Senzi ko
dc.contributor.author Lee, Jae Sung ko
dc.date.available 2015-07-27T05:06:02Z -
dc.date.created 2015-07-24 ko
dc.date.issued 1998-01 -
dc.identifier.citation JOURNAL OF CATALYSIS, v.173, no.1, pp.134 - 144 ko
dc.identifier.issn 0021-9517 ko
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/12733 -
dc.identifier.uri http://www.sciencedirect.com/science/article/pii/S0021951797918984# ko
dc.description.abstract Hydrodenitrogenation (HDN) of indole has been studied over Mo2N prepared from MoO3, 12-molybdophosphoric acid (HPA) and MoO3 + P2O5 (a physical mixture of P2O5 and MoO3 with stoichiometry of P to Mo equal to that of HPA). It has been observed that Mo2N is an active catalyst for HDN of indole. It gave comparable activity (per unit mass) to that of Mo-Ni/gamma-Al2O3 but less hydrogen consumption. The initial activity of indole HDN was significantly increased by adding phosphorus in the catalysts despite its unfavorable pore and site blocking effects. However, P-containing Mo2N lost activity more readily than Mo2N itself, The deactivation did not result from carbon but probably was caused by nitrogen deposits from indole and loss of surface area, The bulk structure and morphology of the Mo2N catalysts were not changed after HND of indole, The reaction pathway did nor appear to be altered by adding phosphorus. (C) 1998 Academic Press ko
dc.description.statementofresponsibility close -
dc.language ENG ko
dc.publisher ACADEMIC PRESS INC ELSEVIER SCIENCE ko
dc.subject UNSUPPORTED POWDERS ko
dc.subject SURFACE-AREA ko
dc.subject CATALYSTS ko
dc.subject HYDRODESULFURIZATION ko
dc.subject PHOSPHORUS ko
dc.subject ALUMINA ko
dc.subject THIOPHENE ko
dc.subject TUNGSTEN ko
dc.title Molybdenum nitride and carbide prepared from heteropolyacid II. Hydrodenitrogenation of indole ko
dc.title.alternative Molybdenum nitride and carbide prepared from heteropolyacid II. Hydrodenitrogenation of indole ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-0000510749 ko
dc.identifier.wosid 000071824200014 ko
dc.type.rims ART ko
dc.description.wostc 33 *
dc.description.scopustc 34 *
dc.date.tcdate 2015-12-28 *
dc.date.scptcdate 2015-11-04 *
dc.identifier.doi 10.1006/jcat.1997.1898 ko
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