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DC Field | Value | Language |
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dc.citation.endPage | 212 | - |
dc.citation.number | 3-4 | - |
dc.citation.startPage | 199 | - |
dc.citation.title | APPLIED CATALYSIS B-ENVIRONMENTAL | - |
dc.citation.volume | 7 | - |
dc.contributor.author | Lee, Jae Sung | - |
dc.contributor.author | Choi, Sun Hee | - |
dc.contributor.author | Kim, Ki Dong | - |
dc.contributor.author | Nomura, Masaharu | - |
dc.date.accessioned | 2023-12-22T12:40:22Z | - |
dc.date.available | 2023-12-22T12:40:22Z | - |
dc.date.created | 2015-07-24 | - |
dc.date.issued | 1996-01 | - |
dc.description.abstract | A heterogenized Wacker catalyst system in which pores of a high surface area alumina were filled with an aqueous solution of PdCl2-CuCl2 was active for the oxidation of CO near room temperature. The structure of the catalyst was studied by X-ray absorption fine structure (XAFS). The active phase of Pd was a Pd-II species containing chlorine and, probably, carbonyl ligands. Direct interaction of Pd-Pd or Pd-Cu was not detected. The active phase of copper was found to be solid Cu2Cl(OH)(3) particles in agreement with the X-ray diffraction (XRD) results. The presence of Cu was essential to keep the Pd in the Pd-II state during the reaction. The rates of CO oxidation measured at temperatures of 30-70 degrees C showed a minimum at 40 degrees C, which was attributable partly to an unusual structure change of the active palladium species during the reaction at this temperature | - |
dc.identifier.bibliographicCitation | APPLIED CATALYSIS B-ENVIRONMENTAL, v.7, no.3-4, pp.199 - 212 | - |
dc.identifier.doi | 10.1016/0926-3373(95)00043-7 | - |
dc.identifier.issn | 0926-3373 | - |
dc.identifier.scopusid | 2-s2.0-0030061982 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/12604 | - |
dc.identifier.url | http://www.sciencedirect.com/science/article/pii/0926337395000437 | - |
dc.identifier.wosid | A1996TZ79800003 | - |
dc.language | 영어 | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.title.alternative | Supported PdCl2-CuCl2 catalysts for carbon monoxide oxidation .2. XAFS characterization | - |
dc.title | Supported PdCl2-CuCl2 catalysts for carbon monoxide oxidation .2. XAFS characterization | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
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