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DC Field | Value | Language |
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dc.citation.endPage | 1862 | - |
dc.citation.number | 7 | - |
dc.citation.startPage | 1853 | - |
dc.citation.title | CHEMISTRY OF MATERIALS | - |
dc.citation.volume | 10 | - |
dc.contributor.author | Li, Senzi | - |
dc.contributor.author | Kim, Won Bae | - |
dc.contributor.author | Lee, Jae Sung | - |
dc.date.accessioned | 2023-12-22T12:36:01Z | - |
dc.date.available | 2023-12-22T12:36:01Z | - |
dc.date.created | 2015-07-24 | - |
dc.date.issued | 1998-07 | - |
dc.description.abstract | A temperature-programmed reaction method was employed to investigate the solid-state transformation of molybdenum oxides to carbides or nitrides by reaction with various reacting gases such as H-2 and NH3 and the mixtures of CH4 and H-2 (CH4/H-2 1/4), CO and H-2 (CO/H-2 1/4), and N-2 and H-2 (N-2/H-2 1/3 and 3/1). The solid-state transformation of MoO3 to nitride by reaction with NH3 was topotactic. In contrast, MoO3 took a nontopotactic route by reaction with the other gases or their mixtures, leading to products that were thermodynamically stable under the investigated conditions. For the synthesis to take a topotactic route it required that the carburization or nitridation occurs in the initial stage of reduction to form intermediate phases containing carbon or nitrogen at low temperatures | - |
dc.identifier.bibliographicCitation | CHEMISTRY OF MATERIALS, v.10, no.7, pp.1853 - 1862 | - |
dc.identifier.doi | 10.1021/cm9800229 | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.scopusid | 2-s2.0-0001053945 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/12584 | - |
dc.identifier.url | http://pubs.acs.org/doi/abs/10.1021/cm9800229 | - |
dc.identifier.wosid | 000075019300021 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title.alternative | Effect of the reactive gas on the solid-state transformation of molybdenum trioxide to carbides and nitrides | - |
dc.title | Effect of the reactive gas on the solid-state transformation of molybdenum trioxide to carbides and nitrides | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
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