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Lee, Jae Sung
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Pt/WC as an anode catalyst for PEMFC: Activity and CO tolerance

Alternative Title
Pt/WC as an anode catalyst for PEMFC: Activity and CO tolerance
Author(s)
Ham, Dong JinKim, Young KwonHan, Seung HyunLee, Jae Sung
Issued Date
2008-03
DOI
10.1016/j.cattod.2007.12.076
URI
https://scholarworks.unist.ac.kr/handle/201301/12554
Fulltext
http://www.sciencedirect.com/science/article/pii/S0920586107008371
Citation
CATALYSIS TODAY, v.132, no.1-4, pp.117 - 122
Abstract
A mesoporous tungsten carbide of WC-phase was synthesized by using ammonium meta tungstate as tungsten precursor and resorcinol-formaldehyde polymer as carbon source in the presence of a surfactant. The platinum supported on this material with a low loading (7.5 wt%) served as an effective CO tolerant electro anode catalyst. The Pt[WC catalyst showed two times higher activity per mass of Pt for hydrogen electrooxidation compared to a commercial Pt/C catalyst (E-Teck). In addition, it exhibited much improved resistance to CO poisoning relative to the Pt/C catalyst. Since the catalyst is also stable in electrochemical environment, it could become an alternative anode catalyst for PEMFC. (C) 2007 Elsevier B.V. All rights reserved
Publisher
ELSEVIER SCIENCE BV
ISSN
0920-5861
Keyword (Author)
Pu/WCmesoporousCO tolerancehydrogen oxidationfuel cells
Keyword
MOLYBDENUM CARBIDE CATALYSTSTUNGSTEN CARBIDEMETHANOL OXIDATIONACIDELECTROCATALYSTSPTRU

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