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Lee, Jae Sung
Eco-friendly Catalysis & Energy Lab.
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dc.citation.endPage 280 -
dc.citation.number 2 -
dc.citation.startPage 267 -
dc.citation.title APPLIED CATALYSIS -
dc.citation.volume 75 -
dc.contributor.author WOO, Hee Chul -
dc.contributor.author PARK, Ki Yeop -
dc.contributor.author KIM, Young Gul -
dc.contributor.author NAM, In-Sik -
dc.contributor.author CHUNG, Jong Shik -
dc.contributor.author Lee, Jae Sung -
dc.date.accessioned 2023-12-22T13:08:11Z -
dc.date.available 2023-12-22T13:08:11Z -
dc.date.created 2015-07-23 -
dc.date.issued 1991-08 -
dc.description.abstract Unsupported molybdenum carbides, beta-Mo2C and alpha-MoC1-x, promoted by K2CO3 were studied as catalysts for carbon monoxide-hydrogen reactions at 573 K and 8.0 MPa. Unpromoted molybdenum carbides produce mainly hydrocarbons of C1-C12 under these conditions. Addition of K2CO3 as a promoter, however, greatly enhances the selectivity to alcohols composed of linear C1-C7. Compared with better known alkali-promoted MoS2 catalysts, carbide catalysts show higher selectivities of C2-C7 alcohols. The carbon number distributions of both hydrocarbon and alcohol are consistent with the Schulz-Flory equation. Unlike MoS2 catalysts, the addition of hydrogen sulfide in the feed over molybdenum carbide catalysts causes a gradual decrease in activity and selectivity for alcohols with reaction time -
dc.identifier.bibliographicCitation APPLIED CATALYSIS, v.75, no.2, pp.267 - 280 -
dc.identifier.doi 10.1016/S0166-9834(00)83136-X -
dc.identifier.issn 0166-9834 -
dc.identifier.scopusid 2-s2.0-0026202685 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/12542 -
dc.identifier.url http://www.sciencedirect.com/science/article/pii/S016698340083136X -
dc.identifier.wosid A1991GC37700005 -
dc.language 영어 -
dc.publisher Elsevier BV -
dc.title.alternative MIXED ALCOHOL SYNTHESIS FROM CARBON-MONOXIDE AND DIHYDROGEN OVER POTASSIUM-PROMOTED MOLYBDENUM CARBIDE CATALYSTS -
dc.title MIXED ALCOHOL SYNTHESIS FROM CARBON-MONOXIDE AND DIHYDROGEN OVER POTASSIUM-PROMOTED MOLYBDENUM CARBIDE CATALYSTS -
dc.type Article -
dc.description.journalRegisteredClass scopus -

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