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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 280 | - |
dc.citation.number | 2 | - |
dc.citation.startPage | 267 | - |
dc.citation.title | APPLIED CATALYSIS | - |
dc.citation.volume | 75 | - |
dc.contributor.author | WOO, Hee Chul | - |
dc.contributor.author | PARK, Ki Yeop | - |
dc.contributor.author | KIM, Young Gul | - |
dc.contributor.author | NAM, In-Sik | - |
dc.contributor.author | CHUNG, Jong Shik | - |
dc.contributor.author | Lee, Jae Sung | - |
dc.date.accessioned | 2023-12-22T13:08:11Z | - |
dc.date.available | 2023-12-22T13:08:11Z | - |
dc.date.created | 2015-07-23 | - |
dc.date.issued | 1991-08 | - |
dc.description.abstract | Unsupported molybdenum carbides, beta-Mo2C and alpha-MoC1-x, promoted by K2CO3 were studied as catalysts for carbon monoxide-hydrogen reactions at 573 K and 8.0 MPa. Unpromoted molybdenum carbides produce mainly hydrocarbons of C1-C12 under these conditions. Addition of K2CO3 as a promoter, however, greatly enhances the selectivity to alcohols composed of linear C1-C7. Compared with better known alkali-promoted MoS2 catalysts, carbide catalysts show higher selectivities of C2-C7 alcohols. The carbon number distributions of both hydrocarbon and alcohol are consistent with the Schulz-Flory equation. Unlike MoS2 catalysts, the addition of hydrogen sulfide in the feed over molybdenum carbide catalysts causes a gradual decrease in activity and selectivity for alcohols with reaction time | - |
dc.identifier.bibliographicCitation | APPLIED CATALYSIS, v.75, no.2, pp.267 - 280 | - |
dc.identifier.doi | 10.1016/S0166-9834(00)83136-X | - |
dc.identifier.issn | 0166-9834 | - |
dc.identifier.scopusid | 2-s2.0-0026202685 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/12542 | - |
dc.identifier.url | http://www.sciencedirect.com/science/article/pii/S016698340083136X | - |
dc.identifier.wosid | A1991GC37700005 | - |
dc.language | 영어 | - |
dc.publisher | Elsevier BV | - |
dc.title.alternative | MIXED ALCOHOL SYNTHESIS FROM CARBON-MONOXIDE AND DIHYDROGEN OVER POTASSIUM-PROMOTED MOLYBDENUM CARBIDE CATALYSTS | - |
dc.title | MIXED ALCOHOL SYNTHESIS FROM CARBON-MONOXIDE AND DIHYDROGEN OVER POTASSIUM-PROMOTED MOLYBDENUM CARBIDE CATALYSTS | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
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