File Download
There are no files associated with this item.
SFX Link
- Find it @ UNIST can give you direct access to the published full text of this article. (UNISTARs only)
- Lee, Jae Sung
- Eco-friendly Catalysis & Energy Lab.
Views & Downloads
Detailed Information
Cited time in 
Cited time in 
Cited time in
Metadata Downloads
Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.citation.endPage | 281 | - |
| dc.citation.number | 2 | - |
| dc.citation.startPage | 269 | - |
| dc.citation.title | APPLIED CATALYSIS A-GENERAL | - |
| dc.citation.volume | 247 | - |
| dc.contributor.author | Park, Eun Duck | - |
| dc.contributor.author | Hwang, Yoo-Shik | - |
| dc.contributor.author | Lee, Chul Woo | - |
| dc.contributor.author | Lee, Jae Sung | - |
| dc.date.accessioned | 2023-12-22T11:10:44Z | - |
| dc.date.available | 2023-12-22T11:10:44Z | - |
| dc.date.created | 2015-07-24 | - |
| dc.date.issued | 2003-07 | - |
| dc.description.abstract | Copper- and vanadium-catalyzed oxidation of methane into methyl trifluoroacetate and formic acid with in situ generated H2O2 from H-2 and O-2 over Pd/C was investigated in trifluoroacetic acid (TFA) and/or trifluoroacetic anhydride (TFAA) as a solvent. Metallic palladium was responsible for the in situ generation of hydrogen peroxide from dihydrogen and dioxygen. Divalent copper hydroperoxide and monoperoxomonovanadate, VO(O-2)(+), seemed to be related to C-H bond activation. The radical chain reaction did not occur in either copper- or vanadium-catalyzed methane oxidation. However, methyl radical appeared to be produced in vanadium system but not in copper system. (C) 2003 Elsevier Science B.V. All rights reserved | - |
| dc.identifier.bibliographicCitation | APPLIED CATALYSIS A-GENERAL, v.247, no.2, pp.269 - 281 | - |
| dc.identifier.doi | 10.1016/S0926-860X(03)00125-X | - |
| dc.identifier.issn | 0926-860X | - |
| dc.identifier.scopusid | 2-s2.0-0038374169 | - |
| dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/12525 | - |
| dc.identifier.url | http://www.sciencedirect.com/science/article/pii/S0926860X0300125X# | - |
| dc.identifier.wosid | 000184520300008 | - |
| dc.language | 영어 | - |
| dc.publisher | ELSEVIER SCIENCE BV | - |
| dc.title.alternative | Copper- and vanadium-catalyzed methane oxidation into oxygenates with in situ generated H2O2 over Pd/C | - |
| dc.title | Copper- and vanadium-catalyzed methane oxidation into oxygenates with in situ generated H2O2 over Pd/C | - |
| dc.type | Article | - |
| dc.description.journalRegisteredClass | scopus | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.