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DC Field | Value | Language |
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dc.citation.endPage | 11883 | - |
dc.citation.number | 24 | - |
dc.citation.startPage | 11878 | - |
dc.citation.title | JOURNAL OF PHYSICAL CHEMISTRY B | - |
dc.citation.volume | 110 | - |
dc.contributor.author | Wang, CM | - |
dc.contributor.author | Kwak, Jahun | - |
dc.contributor.author | Kim, DH | - |
dc.contributor.author | Szanyi, J | - |
dc.contributor.author | Sharma, R | - |
dc.contributor.author | Thevuthasan, S | - |
dc.contributor.author | Peden, CHF | - |
dc.date.accessioned | 2023-12-22T10:06:16Z | - |
dc.date.available | 2023-12-22T10:06:16Z | - |
dc.date.created | 2015-07-21 | - |
dc.date.issued | 2006-06 | - |
dc.description.abstract | A key question for the BaO-based NOx storage/reduction catalyst system is the morphological evolution of the catalyst particles during the uptake and release of NOx. Notably, because the formed product during NOx uptake, Ba(NO3)(2), requires a lattice expansion from BaO, one can anticipate that significant structural rearrangements are possible during the storage/reduction processes. Associated with the small crystallite size of high-surface area gamma-Al2O3, it is difficult to extract structural and morphological features of Ba(NO3)(2) supported on gamma-Al2O3 by any direct imaging method, including transmission electron microscopy. In this work, by choosing a model system of Ba(NO3)(2) particles supported on single-crystal alpha-Al2O3, we have investigated the structural and morphological features of Ba( NO3)(2) as well as the formation of BaO from Ba(NO3)(2) during the thermal release of NOx, using ex-situ and in-situ TEM imaging, electron diffraction, energy dispersive spectroscopy (EDS), and Wulff shape construction. We find that Ba(NO3)(2) supported on alpha-Al2O3 possesses a platelet morphology, with the interface and facets being invariably the eight {111} planes. Formation of the platelet structure leads to an enlarged interface area between Ba(NO3)(2) and alpha-Al2O3, indicating that the interfacial energy is lower than the Ba( NO3) 2 surface free energy. In fact, Wulff shape constructions indicate that the interfacial energy is similar to 1/4 of the {111} surface free energy of Ba(NO3)(2). The orientation relationship between Ba(NO3)(2) and the alpha-Al2O3 is alpha-Al2O3[0001]// Ba(NO3)(2)[111] and alpha-Al2O3(1- 210)// Ba( NO3) 2( 110). Thus, the results clearly demonstrate dramatic morphology changes in these materials during NOx release processes. Such changes are expected to have significant consequences for the operation of the practical NOx storage/reduction catalyst technology | - |
dc.identifier.bibliographicCitation | JOURNAL OF PHYSICAL CHEMISTRY B, v.110, no.24, pp.11878 - 11883 | - |
dc.identifier.doi | 10.1021/jp060235i | - |
dc.identifier.issn | 1520-6106 | - |
dc.identifier.scopusid | 2-s2.0-33745700137 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/12431 | - |
dc.identifier.url | http://pubs.acs.org/doi/abs/10.1021/jp060235i | - |
dc.identifier.wosid | 000238284600039 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title.alternative | Morphological evolution of Ba(NO3)(2) supported on alpha-Al2O3(0001): An in situ TEM study | - |
dc.title | Morphological evolution of Ba(NO3)(2) supported on alpha-Al2O3(0001): An in situ TEM study | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | NOX STORAGE | - |
dc.subject.keywordPlus | FT-IR | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | ADSORPTION | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | BAO/AL2O3 | - |
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