Excellent sulfur resistance of Pt/BaO/CeO(2) lean NO(x) trap catalysts
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kwak, Ja Hun | ko |
dc.contributor.author | Kim, Do Heui | ko |
dc.contributor.author | Szanyi, Janos | ko |
dc.contributor.author | Peden, Charles H. F. | ko |
dc.date.available | 2015-07-23T02:12:29Z | - |
dc.date.created | 2015-07-21 | ko |
dc.date.issued | 2008-12 | - |
dc.identifier.citation | APPLIED CATALYSIS B-ENVIRONMENTAL, v.84, no.3-4, pp.545 - 551 | ko |
dc.identifier.issn | 0926-3373 | ko |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/12347 | - |
dc.identifier.uri | http://www.sciencedirect.com/science/article/pii/S0926337308001823 | ko |
dc.description.abstract | In this work, we investigated the NO(x) storage behavior of Pt/BaO/CeO(2) catalysts, especially in the presence of SO(2). High surface area CeO(2) (similar to 110 m(2)/g) with a rod like morphology was synthesized and used as a support. The Pt/BaO/CeO(2) sample demonstrated slightly higher NO(x) uptake in the entire temperature range studied compared with Pt/BaO/gamma-Al(2)O(3). More importantly, this ceria-based catalyst showed higher sulfur tolerance than the alumina-based one. The time of complete NO(x) uptake was maintained even after exposing the sample to similar to 3 g/L of SO(2). The same sulfur exposure, on the other hand, eliminated the complete NO(x) uptake time on the alumina-based NO(x) storage catalysts. TEM images show no evidence of either Pt sintering or BaS phase formation during reductive de-sulfation up to 600 degrees C on the ceria-based catalyst, while the same process over the alumina-based catalyst resulted in both a significant increase in the average Pt cluster size and the agglomeration of a newly formed BaS phase into large crystallites. XPS results revealed the presence of about five times more residual sulfur after reductive de-sulfation at 600 degrees C on the alumina-based catalysts in comparison with the ceria-based ones. All of these results strongly support that, besides their superior intrinsic NO(x) uptake properties, ceria-based catalysts have (a) much higher sulfur tolerance and (b) excellent resistance against Pt sintering when they are compared to the widely used alumina-based catalysts. (C) 2008 Elsevier B.V. All rights reserved | ko |
dc.description.statementofresponsibility | close | - |
dc.language | ENG | ko |
dc.publisher | ELSEVIER SCIENCE BV | ko |
dc.subject | STORAGE-REDUCTION | ko |
dc.subject | PT/BAO/AL2O3 | ko |
dc.subject | MECHANISM | ko |
dc.subject | TEMPERATURE | ko |
dc.subject | STABILITY | ko |
dc.subject | PLATINUM | ko |
dc.subject | WATER | ko |
dc.subject | OXIDE | ko |
dc.title | Excellent sulfur resistance of Pt/BaO/CeO(2) lean NO(x) trap catalysts | ko |
dc.title.alternative | Excellent sulfur resistance of Pt/BaO/CeO(2) lean NO(x) trap catalysts | ko |
dc.type | ARTICLE | ko |
dc.identifier.scopusid | 2-s2.0-53949106531 | ko |
dc.identifier.wosid | 000261123600028 | ko |
dc.type.rims | ART | ko |
dc.description.wostc | 35 | * |
dc.description.scopustc | 38 | * |
dc.date.tcdate | 2015-12-28 | * |
dc.date.scptcdate | 2015-11-04 | * |
dc.identifier.doi | 10.1016/j.apcatb.2008.05.009 | ko |
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