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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 29 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 27 | - |
dc.citation.title | JOURNAL OF PHYSICAL CHEMISTRY B | - |
dc.citation.volume | 109 | - |
dc.contributor.author | Szanyi, Ja´nos | - |
dc.contributor.author | Kwak, Jahun | - |
dc.contributor.author | Kim, Do Heui | - |
dc.contributor.author | Burton, Sarah D. | - |
dc.contributor.author | Peden, Charles H. F. | - |
dc.date.accessioned | 2023-12-22T10:39:02Z | - |
dc.date.available | 2023-12-22T10:39:02Z | - |
dc.date.created | 2015-07-15 | - |
dc.date.issued | 2005-01 | - |
dc.description.abstract | Temperature programmed desorption, infrared spectroscopy, and N-15 solid state NMR spectroscopy were used to characterize the nature of the nitrate species formed on Al2O3 and BaO/Al2O3 NOx storage/reduction materials. Two distinctly different nitrate species were found: surface nitrates that are associated with a monolayer BaO on the alumina support, and a bulk-like nitrate that forms on this thin BaO layer. The surface nitrates desorb as NO2 at lower temperatures than do the bulk-like nitrates, which decompose as NO+O-2 at higher temperatures. The amount of NOx stored in the monolayer nitrate is proportional to the surface area of the catalyst, while that in the bulk nitrate increases with BaO coverage | - |
dc.identifier.bibliographicCitation | JOURNAL OF PHYSICAL CHEMISTRY B, v.109, no.1, pp.27 - 29 | - |
dc.identifier.doi | 10.1021/jp044993p | - |
dc.identifier.issn | 1520-6106 | - |
dc.identifier.scopusid | 2-s2.0-12344257037 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/12159 | - |
dc.identifier.url | http://pubs.acs.org/doi/abs/10.1021/jp044993p | - |
dc.identifier.wosid | 000226213200007 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title.alternative | NO2 adsorption on BaO/Al2O3: The nature of nitrate species | - |
dc.title | NO2 adsorption on BaO/Al2O3: The nature of nitrate species | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
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