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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 8962 | - |
dc.citation.number | 22 | - |
dc.citation.startPage | 8956 | - |
dc.citation.title | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.citation.volume | 70 | - |
dc.contributor.author | Ja-Hyoung Ryu | - |
dc.contributor.author | Cheong-Jin Jang | - |
dc.contributor.author | Yong-Sik Yoo | - |
dc.contributor.author | Sung-Gon Lim | - |
dc.contributor.author | Myongsoo Lee | - |
dc.date.accessioned | 2023-12-22T10:12:06Z | - |
dc.date.available | 2023-12-22T10:12:06Z | - |
dc.date.created | 2015-07-15 | - |
dc.date.issued | 2005-10 | - |
dc.description.abstract | We have investigated supramolecular reactors for the Suzuki coupling reactions of aryl halides with phenyl boronic acids by using self-assembly of amphiphilic rod-coil molecules in aqueous solution at room temperature. All the rod-coil molecules synthesized in this work showed to self-assemble into discrete micelles consisting of aromatic rod bundles encapsulated by hydrophilic poly(ethylene oxide) coils. We present a comparative study of rod-coil molecules' efficiency as supramolecular reactors for Suzuki coupling reaction. The closed-packed aromatic bundles play an efficient role in supramolecular reactors for the coupling reactions at room temperature. The supramolecular reactor based on hexa-p-phenylene confers unprecedented activity, allowing reactions to be performed at very low catalyst levels, without conventional heating or microwave | - |
dc.identifier.bibliographicCitation | JOURNAL OF ORGANIC CHEMISTRY, v.70, no.22, pp.8956 - 8962 | - |
dc.identifier.doi | 10.1021/jo051398q | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.scopusid | 2-s2.0-27444431592 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/12151 | - |
dc.identifier.url | http://pubs.acs.org/doi/abs/10.1021/jo051398q | - |
dc.identifier.wosid | 000232909300041 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title.alternative | Supramolecular reactor in an aqueous environment: Aromatic cross Suzuki coupling reaction at room temperature | - |
dc.title | Supramolecular reactor in an aqueous environment: Aromatic cross Suzuki coupling reaction at room temperature | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | ROD-COIL MOLECULES | - |
dc.subject.keywordPlus | LIQUID-CRYSTALLINE ASSEMBLIES | - |
dc.subject.keywordPlus | BLOCK-COPOLYMERS | - |
dc.subject.keywordPlus | DIBLOCK COPOLYMERS | - |
dc.subject.keywordPlus | ORGANIZATION | - |
dc.subject.keywordPlus | ENCAPSULATION | - |
dc.subject.keywordPlus | METHODOLOGY | - |
dc.subject.keywordPlus | COLUMNAR | - |
dc.subject.keywordPlus | MEDIA | - |
dc.subject.keywordPlus | GUEST | - |
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