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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 1688 | - |
dc.citation.number | 19 | - |
dc.citation.startPage | 1684 | - |
dc.citation.title | MACROMOLECULAR RAPID COMMUNICATIONS | - |
dc.citation.volume | 27 | - |
dc.contributor.author | Park, Myoung-Hwan | - |
dc.contributor.author | Ryu, Ja-Hyoung | - |
dc.contributor.author | Lee, Eunji | - |
dc.contributor.author | Han, Kyung-Hee | - |
dc.contributor.author | Chung, Yeon-Wook | - |
dc.contributor.author | Cho, Byoung-Ki | - |
dc.contributor.author | Lee, Myongsoo | - |
dc.date.accessioned | 2023-12-22T09:41:23Z | - |
dc.date.available | 2023-12-22T09:41:23Z | - |
dc.date.created | 2015-07-15 | - |
dc.date.issued | 2006-10 | - |
dc.description.abstract | We have prepared hexa-p-phenylene based rod-coil molecules with identical coil volume fractions, but different poly(propylene oxide) (PPO) coil architectures (linear versus dibranched), and investigated their self-assembling behavior in the solid state by small angle X-ray scattering (SAXS) and transmission electron microscopy (TEM) techniques. Rod-coil molecules with a linear PPO coil showed a honeycomb-like lamellar assembly of rod segments with hexagonally arrayed PPO coil perforations. In contrast, the rod-coil molecules with dibranched PPO coils self-organized into rod bundles with a body centered tetragonal symmetry surrounded by a PPO coil matrix. These results demonstrate that the steric hindrance at the rod/coil interface arising from coil architectural variation is a dominant parameter governing supramolecular rod assembly in the rod-coil system | - |
dc.identifier.bibliographicCitation | MACROMOLECULAR RAPID COMMUNICATIONS, v.27, no.19, pp.1684 - 1688 | - |
dc.identifier.doi | 10.1002/marc.200600445 | - |
dc.identifier.issn | 1022-1336 | - |
dc.identifier.scopusid | 2-s2.0-33750086069 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/12139 | - |
dc.identifier.url | http://onlinelibrary.wiley.com/doi/10.1002/marc.200600445/abstract | - |
dc.identifier.wosid | 000241305100011 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title.alternative | Chain architecture dependent 3-dimensional supramolecular assembly of rod-coil molecules with a conjugated hexa-p-phenylene rod | - |
dc.title | Chain architecture dependent 3-dimensional supramolecular assembly of rod-coil molecules with a conjugated hexa-p-phenylene rod | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | body centered tetragonal micellar structure | - |
dc.subject.keywordAuthor | honeycomb-like lamellar structure | - |
dc.subject.keywordAuthor | rod-coil molecules | - |
dc.subject.keywordAuthor | self-assembly | - |
dc.subject.keywordAuthor | supramolecular structures | - |
dc.subject.keywordPlus | STAR BLOCK-COPOLYMERS | - |
dc.subject.keywordPlus | DIBLOCK COPOLYMERS | - |
dc.subject.keywordPlus | MICROPHASE SEPARATION | - |
dc.subject.keywordPlus | FLEXIBLE DENDRONS | - |
dc.subject.keywordPlus | ORGANIZATION | - |
dc.subject.keywordPlus | POLYSTYRENE | - |
dc.subject.keywordPlus | MORPHOLOGY | - |
dc.subject.keywordPlus | DENDRIMERS | - |
dc.subject.keywordPlus | OLIGOMERS | - |
dc.subject.keywordPlus | FILMS | - |
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