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dc.citation.endPage 473 -
dc.citation.number 2 -
dc.citation.startPage 472 -
dc.citation.title JOURNAL OF THE AMERICAN CHEMICAL SOCIETY -
dc.citation.volume 126 -
dc.contributor.author Kaizer, Jozsef -
dc.contributor.author Klinker, Eric J. -
dc.contributor.author Oh, Na Young -
dc.contributor.author Rohde, Jan-Uwe -
dc.contributor.author Song, Woon Ju -
dc.contributor.author Stubna, Audria -
dc.contributor.author Kim, Jinheung -
dc.contributor.author Munck, Eckard -
dc.contributor.author Nam, Wonwoo -
dc.contributor.author Que, Lawrence Jr. -
dc.date.accessioned 2023-12-22T11:07:13Z -
dc.date.available 2023-12-22T11:07:13Z -
dc.date.created 2015-07-05 -
dc.date.issued 2004-01 -
dc.description.abstract Nonheme oxoiron(IV) complexes of two pentadentate ligands, N4Py (N,N-bis(2-pyridylmethyl)-bis(2-pyridyl)methylamine) and Bn-tpen (N-benzyl-N,N′,N′-tris(2-pyridylmethyl)-1,2-diaminoethane), have been generated and found to have spectroscopic properties similar to the closely related tetradentate TPA (tris(2-pyridylmethyl)amine) complex reported earlier. However, unlike the TPA complex, the pentadentate complexes have a considerable lifetime at room temperature. This greater thermal stability has allowed the hydroxylation of alkanes with C-H bonds as strong as 99.3 kcal/mol to be observed at room temperature. Furthermore, a large deuterium KIE value is found in the oxidation of ethylbenzene. These observations lend strong credence to postulated mechanisms of mononuclear nonheme iron enzymes that invoke the intermediacy of oxoiron(IV) species. Copyright © 2004 American Chemical Society. -
dc.identifier.bibliographicCitation JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.126, no.2, pp.472 - 473 -
dc.identifier.doi 10.1021/ja037288n -
dc.identifier.issn 0002-7863 -
dc.identifier.scopusid 2-s2.0-0347717615 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/11982 -
dc.identifier.url http://pubs.acs.org/doi/abs/10.1021/ja037288n -
dc.identifier.wosid 000188197800032 -
dc.language 영어 -
dc.publisher AMER CHEMICAL SOC -
dc.title Nonheme (FeO)-O-IV complexes that can oxidize the C-H bonds of cyclohexane at room temperature -
dc.type Article -
dc.description.journalRegisteredClass scopus -

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