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DC Field | Value | Language |
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dc.citation.endPage | 5726 | - |
dc.citation.number | 14 | - |
dc.citation.startPage | 5720 | - |
dc.citation.title | INORGANIC CHEMISTRY | - |
dc.citation.volume | 46 | - |
dc.contributor.author | Rohde, Jan-Uwe | - |
dc.contributor.author | Betley, Theodore A. | - |
dc.contributor.author | Jackson, Timothy A. | - |
dc.contributor.author | Saouma, Caroline T. | - |
dc.contributor.author | Peters, Jonas C. | - |
dc.contributor.author | Que, Lawrence, Jr. | - |
dc.date.accessioned | 2023-12-22T09:12:12Z | - |
dc.date.available | 2023-12-22T09:12:12Z | - |
dc.date.created | 2015-07-03 | - |
dc.date.issued | 2007-07 | - |
dc.description.abstract | X-ray absorption spectroscopy has been used to characterize the novel nitridoiron(IV) units in two [PhBP3R]Fe(N) complexes (R = iPr and CyCH2) and obtain direct spectroscopic evidence for a very short Fe-N distance. The distance of 1.51-1.55 A reflects the presence of an FeN triple bond in accord with the observed FeN vibration observed for one of these species (nu(FeN) = 1034 cm(-1)). This highly covalent bonding interaction results in the appearance of an unusually intense pre-edge peak, whose estimated area of 100(20) units is much larger than those of the related tetrahedral complexes with Fe-I-N-2-Fe-I, Fe-II-NPh2, and Fe(III)NAd motifs, and those of recently described six-coordinate (FeN)-N-V and (FeN)-N-VI complexes. The observation that the Fe-IV-N distances of two [PhBP3R]Fe(N) complexes are shorter than the Fe-IV-O bond lengths of oxoiron(IV) complexes may be rationalized on the basis of the greater pi basicity of the nitrido ligand than the oxo ligand and a lower metal coordination number for the Fe(N) complex | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY, v.46, no.14, pp.5720 - 5726 | - |
dc.identifier.doi | 10.1021/ic700818q | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.scopusid | 2-s2.0-34547190214 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/11975 | - |
dc.identifier.url | http://pubs.acs.org/doi/abs/10.1021/ic700818q | - |
dc.identifier.wosid | 000247623000041 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | XAS characterization of a Nitridoiron(IV) complex with a very short fe-n bond | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | IRON IMIDE | - |
dc.subject.keywordPlus | NONHEME | - |
dc.subject.keywordPlus | COORDINATION | - |
dc.subject.keywordPlus | SPECTROSCOPY | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | ENERGIES | - |
dc.subject.keywordPlus | FIXATION | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | STATE | - |
dc.subject.keywordPlus | SITE | - |
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