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Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)
  • Crystal Engineering
  • Supramolecular coordination chemistry

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Topology analysis of metal-organic frameworks based on metal-organic polyhedra as secondary or tertiary building units

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Title
Topology analysis of metal-organic frameworks based on metal-organic polyhedra as secondary or tertiary building units
Author
Kim, DongwookLiu, XinfangLah, Myoung Soo
Issue Date
2015-04
Publisher
Royal Society of Chemistry
Citation
INORGANIC CHEMISTRY FRONTIERS, v.2, no.4, pp.336 - 360
Abstract
The structural features of metal-organic frameworks (MOFs) can be analyzed based on the network structure (net) topology, composed of nodes and linkers. The connectivity and site symmetry of a node are probably the most important factors affecting the net topology of MOFs. Many MOFs with multiple nodes of different connectivity and site symmetry have complicated net topologies. However, the underlying net topology of some complicated MOFs could be analyzed using a hierarchical simplification approach. The underlying net topology of complicated MOFs with multi-connected nodes could be analyzed using a metal-organic polyhedron composed of multiple nodes as either a secondary building unit or a tertiary building unit. The simplified net topology provides better insight into the structural features of the complicated MOF structures and could be utilized in designing new MOF structures with known and/or unprecedented net topologies.
URI
https://scholarworks.unist.ac.kr/handle/201301/11816
URL
http://pubs.rsc.org/en/content/articlehtml/2015/qi/c4qi00236a
DOI
10.1039/C4QI00236A
ISSN
2052-1553
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