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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 842 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | 838 | - |
dc.citation.title | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.volume | 36 | - |
dc.contributor.author | Sarkar, Shuranjan | - |
dc.contributor.author | Moon, Dohyun | - |
dc.contributor.author | Kim, Seog K. | - |
dc.contributor.author | Lah, Myoung Soo | - |
dc.contributor.author | Lee, Hong-In | - |
dc.date.accessioned | 2023-12-22T01:37:18Z | - |
dc.date.available | 2023-12-22T01:37:18Z | - |
dc.date.created | 2015-07-02 | - |
dc.date.issued | 2015-03 | - |
dc.description.abstract | A chiral nickel(II) complex, [Ni(II)H3L](ClO4)(2) (1), with an achiral ligand H3L (=tris{2-(4-imidazolyl) methyli-minoethyl} amine) was synthesized by in situ reaction between nickel(II) perchlorate hexahydrate and a condensation mixture of 4-imidazolecarboxaldehyde and tris(2-aminoethyl) amine. Single crystal X-ray analysis revealed that the H3L ligand hexadentately binds to Ni(II) ion through three Schiff-base imine N atoms and three imidazole N atoms with distorted octahedral geometry. Both single-crystal X-ray diffraction and circular dichroism investigations found that the crystal of complex 1 was an enantiopure conglomerate. The hydrogen-bond network of NimidazoleH center dot center dot center dot O-ClO4 center dot center dot center dot HNimidazole induced spontaneous resolution to form the conglomerate. The capped tripod-shaped [Ni(II)H3L](2+) complex ions are hydrogen-bonded in a tail-to-tail mode and array in an up-and-down manner repeatedly to honeycomb an extended two-dimensional homochiral network with trigonal voids | - |
dc.identifier.bibliographicCitation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.36, no.3, pp.838 - 842 | - |
dc.identifier.doi | 10.1002/bkcs.10157 | - |
dc.identifier.issn | 1229-5949 | - |
dc.identifier.scopusid | 2-s2.0-84936948713 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/11813 | - |
dc.identifier.wosid | 000353574800023 | - |
dc.language | 영어 | - |
dc.publisher | KOREAN CHEMICAL SOC | - |
dc.title | Spontaneous Resolution Induced by a Chiral Ni(II) Complex with an Achiral Tripodal Ligand | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | Ni(II) complex | - |
dc.subject.keywordAuthor | Spontaneous resolution | - |
dc.subject.keywordAuthor | Conglomerate | - |
dc.subject.keywordPlus | 3 IMIDAZOLE GROUPS | - |
dc.subject.keywordPlus | PROTONATION STATE | - |
dc.subject.keywordPlus | IRON COMPLEXES | - |
dc.subject.keywordPlus | RADII | - |
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