Carbon nanotube dispersion and exfoliation in polypropylene and structure and properties of the resulting composites

Abstract

Nitric acid treated single and multi wall carbon nanotubes (SWNT and MWNT) have been dispersed in polypropylene using maleic anhydride grafted polypropylene (MA-g-PP) and butanol/xylene solvent mixture. SWNT exfoliation was characterized by Raman and UV-vis-NIR spectroscopies. Evidence for hydrogen bonding between maleic anhydride grafted polypropylene and nitric acid treated nanotubes was obtained using infrared spectroscopy. Polypropylene/carbon nanotube composites were melt-spun into fibers. Dynamic mechanical studies show that for fibers containing 0.1 wt% SWNT, storage modulus increased by 5 GPa at -140 °C and by about 1 GPa at 100 °C, suggesting temperature dependent interfacial strength. The crystallization behavior has been monitored using differential scanning calorimetry and optical microscopy. Control fibers exhibited 27% shrinkage at 160 °C, while the shrinkage in the composite fibers was less than 5%. Fibers heat-treated to 170 °C show very narrow polypropylene melting peak (peak width about 1 °C). ⓒ 2008 Elsevier Ltd. All rights reserved.