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Chae, Han Gi
Polymer nano-composites and Carbon Fiber Laboratory (P&C Lab)
Research Interests
  • Polymer Physics/ Processing, Carbon Nano-materials, Ultra high performance/ multifuctional nano-composites, Smart textile/ fiber

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Interfacial crystallization in gel-spun poly (vinyl alcohol)/single-wall carbon nanotube composite fibers

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dc.contributor.author Minus, Marilyn L. ko
dc.contributor.author Chae, Han Gi ko
dc.contributor.author Kumar, Satish ko
dc.date.available 2015-01-29T04:23:39Z -
dc.date.created 2014-11-17 ko
dc.date.issued 2009-11 -
dc.identifier.citation MACROMOLECULAR CHEMISTRY AND PHYSICS, v.210, no.21, pp.1799 - 1808 ko
dc.identifier.issn 1022-1352 ko
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/10345 -
dc.identifier.uri http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=70449503976 ko
dc.description.abstract PVA and PVA/SWNT fibers (PVA=poly(vinyl alcohol), SWNT=single-walled nanotubes) were processed by gel spinning. At 1wt.-% SWNT loading, tensile strength increased from 1.6 GPa for the control PVA to 2.6 GPa for PVA/SWNT composite. Analysis of this data suggests stress of up to ≈116 GPa on the SWNT in the composite fiber. This confirms excellent reinforcement and load transfer of SWNT in the PVA matrix. Tensile modulus of the fiber is also increased from 47 GPa for the control to 70 GPa for the composite. Interfacial studies using high-resolution transmission electron microscopy reveal extended-chain crystal growth of PVA at the PVA-SWNT interface. High SWNT alignment in the fiber is revealed, where the polarized Raman G-band ratio I0° vv/90°vv) is as high as 106. Composite fiber shrinkage in water is reduced by ∼70% when compared to the control PVA fibers. ⓒ 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. ko
dc.description.statementofresponsibility close -
dc.language ENG ko
dc.publisher WILEY-V C H VERLAG GMBH ko
dc.subject Interfaces ko
dc.subject Nanocomposites ko
dc.subject Nucleation ko
dc.subject Poly(vinyl alcohol) ko
dc.subject SWNT ko
dc.title Interfacial crystallization in gel-spun poly (vinyl alcohol)/single-wall carbon nanotube composite fibers ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-70449503976 ko
dc.identifier.wosid 000272070400003 ko
dc.type.rims ART ko
dc.description.wostc 44 *
dc.description.scopustc 47 *
dc.date.tcdate 2015-12-28 *
dc.date.scptcdate 2015-11-04 *
dc.identifier.doi 10.1002/macp.200900223 ko
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