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DC Field | Value | Language |
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dc.citation.endPage | 596 | - |
dc.citation.number | 4 | - |
dc.citation.startPage | 586 | - |
dc.citation.title | ADVANCED FUNCTIONAL MATERIALS | - |
dc.citation.volume | 25 | - |
dc.contributor.author | Yoo, Dohyuk | - |
dc.contributor.author | Nketia-Yawson, Benjamin | - |
dc.contributor.author | Kang, Seok-Ju | - |
dc.contributor.author | Ahn, Hyungju | - |
dc.contributor.author | Shin, Tae Joo | - |
dc.contributor.author | Noh, Yong-Young | - |
dc.contributor.author | Yang, Changduk | - |
dc.date.accessioned | 2023-12-22T01:44:35Z | - |
dc.date.available | 2023-12-22T01:44:35Z | - |
dc.date.created | 2014-12-30 | - |
dc.date.issued | 2015-01 | - |
dc.description.abstract | Considering there is growing interest in the superior charge transport in the (E)-2-(2-(thiophen-2-yl)-vinyl)thiophene (TVT)-based polymer family, an essential step forward is to provide a deep and comprehensive understanding of the structure-property relationships with their polymer analogs. Herein, a carefully chosen set of DPP-TVT-n polymers are reported here, involving TVT and diketopyrrolopyrrole (DPP) units that are constructed in combination with varying thiophene content in the repeat units, where n is the number of thiophene spacer units. Their OFET characteristics demonstrate ambipolar behavior; in particular, with DPP-TVT-0 a nearly balanced hole and electron transport are observed. Interestingly, the majority of the charge-transport properties changed from ambipolar to p-type dominant, together with the enhanced hole mobilities, as the electron-donating thiophene spacers are introduced. Although both the lamellar d-spacings and π-stacking distances of DPP-TVT-n decreased with as the number of thiophene spacers increased, DPP-TVT-1 clearly shows the highest hole mobility (up to 2.96 cm2 V-1 s-1) owing to the unique structural conformations derived from its smaller paracrystalline distortion parameter and narrower plane distribution relative to the others. These in-depth studies should uncover the underlying structure-property relationships in a relevant class of TVT-like semiconductors, shedding light on the future design of top-performing semiconducting polymers. | - |
dc.identifier.bibliographicCitation | ADVANCED FUNCTIONAL MATERIALS, v.25, no.4, pp.586 - 596 | - |
dc.identifier.doi | 10.1002/adfm.201403527 | - |
dc.identifier.issn | 1616-301X | - |
dc.identifier.scopusid | 2-s2.0-85027953507 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/10007 | - |
dc.identifier.url | http://onlinelibrary.wiley.com/doi/10.1002/adfm.201403527/abstract | - |
dc.identifier.wosid | 000348856500010 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | A Timely Synthetic Tailoring of Biaxially Extended Thienylenevinylene-Like Polymers for Systematic Investigation on Field-Effect Transistors | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary; Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter | - |
dc.relation.journalResearchArea | Chemistry; Science & Technology - Other Topics; Materials Science; Physics | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | diketopyrrolopyrrole | - |
dc.subject.keywordAuthor | organic field-effect transistors | - |
dc.subject.keywordAuthor | paracrystalline distortion parameters | - |
dc.subject.keywordAuthor | plane distribution | - |
dc.subject.keywordAuthor | thienylenevinylene | - |
dc.subject.keywordPlus | THIN-FILM TRANSISTORS | - |
dc.subject.keywordPlus | SOLAR-CELLS | - |
dc.subject.keywordPlus | SEMICONDUCTING POLYMERS | - |
dc.subject.keywordPlus | CONJUGATED POLYMERS | - |
dc.subject.keywordPlus | ELECTRON MOBILITIES | - |
dc.subject.keywordPlus | ORGANIC TRANSISTORS | - |
dc.subject.keywordPlus | CHARGE-TRANSPORT | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | AMBIPOLAR | - |
dc.subject.keywordPlus | COPOLYMERS | - |
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