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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 419 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | 415 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 45 | - |
dc.contributor.author | Kwon, Oh Hoon | - |
dc.contributor.author | Lee, YS | - |
dc.contributor.author | Yoo, BK | - |
dc.contributor.author | Jang, DJ | - |
dc.date.accessioned | 2023-12-22T10:09:32Z | - |
dc.date.available | 2023-12-22T10:09:32Z | - |
dc.date.created | 2014-11-13 | - |
dc.date.issued | 2006 | - |
dc.description.abstract | Proton relay in cyclic 7-hydroxyquinoline-(alcohol)2 complexes (see picture) has been explored in nonpolar solvents. The asymmetric triple proton transfer has an unusually large, temperature-independent, and viscosity-dependent kinetic isotope effect. Heavy-atom motions (wavy arrow) of solvent and bridging molecules allow proton tunneling by assisting the complex to reach the optimal precursor configuration. (Chemical Equation Presented) | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.45, no.3, pp.415 - 419 | - |
dc.identifier.doi | 10.1002/anie.200503209 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.scopusid | 2-s2.0-30444454645 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/8775 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=30444454645 | - |
dc.identifier.wosid | 000234604400011 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Excited-state triple proton transfer of 7-hydroxyquinoline along a hydrogen-bonded alcohol chain: vibrationally assisted proton tunneling | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | hydrogen bonds | - |
dc.subject.keywordAuthor | isotope effects | - |
dc.subject.keywordAuthor | N heterocycles | - |
dc.subject.keywordAuthor | proton transfer | - |
dc.subject.keywordAuthor | time-resolved spectroscopy | - |
dc.subject.keywordPlus | METHANOL SOLUTION | - |
dc.subject.keywordPlus | ACETIC-ACID | - |
dc.subject.keywordPlus | BASE-PAIRS | - |
dc.subject.keywordPlus | TAUTOMERIZATION | - |
dc.subject.keywordPlus | SOLVATION | - |
dc.subject.keywordPlus | ISOTOPE | - |
dc.subject.keywordPlus | SPECTROSCOPY | - |
dc.subject.keywordPlus | NMR | - |
dc.subject.keywordPlus | 7-QUINOLINOL | - |
dc.subject.keywordPlus | FLUORESCENCE | - |
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