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- Kwon, Oh Hoon
- Ultrafast Laser Spectroscopy and Nano-microscopy Lab.
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Charge Transfer Assisted by Collective Hydrogen-Bonding Dynamics
- Issued Date
- 2009
- Citation
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.48, no.34, pp.6251 - 6256
- Abstract
- Bipolar disorder: Femtosecond spectroscopy of samples in protic and aprotic solvents of similar polarities reveals that charge-transfer processes are substantially facilitated by the formation of solute-solvent hydrogen-bond networks (see picture). This notion of molecular-specific interactions is not part of the continuum dielectric models of solvation and should be of significance to biological processes such as those of enzymes.
- Publisher
- WILEY-V C H VERLAG GMBH
- ISSN
- 1433-7851
- Keyword (Author)
- charge transfer, femtochemistry, hydrogen-bonding dynamics, solvation dynamics, time-resolved fluorescence
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