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김병수

Kim, Byeong-Su
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Rotaxane-like characteristics of [2]pseudorotaxane complexes of alpha-cyclodextrin and dodecamethylene threading chain derivatives with cationic end groups

Author(s)
Kim, Byeong-SuHong, JI
Issued Date
2002-03
DOI
10.1246/cl.2002.336
URI
https://scholarworks.unist.ac.kr/handle/201301/8453
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0036012119
Citation
CHEMISTRY LETTERS, v.31, no.3, pp.336 - 337
Abstract
We have prepared several threading chain molecules that are capable of producing [2]pseudorotaxane complexes with α-CD. The free energy of activation of site exchange (ΔG‡) of [2]pseudorotaxanes indicates that the [2]pseudorotaxanes have increasingly rotaxane-like characteristics as the number of cationic end groups and the steric hindrance of end groups of an axle increase.
Publisher
CHEMICAL SOC JAPAN
ISSN
0366-7022

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