There are no files associated with this item.
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 2145 | - |
dc.citation.number | 12 | - |
dc.citation.startPage | 2140 | - |
dc.citation.title | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | - |
dc.citation.volume | 2014 | - |
dc.contributor.author | Carson, Cantwell G. | - |
dc.contributor.author | Brunnello, Giuseppe | - |
dc.contributor.author | Lee, Seung Geol | - |
dc.contributor.author | Jang, Seung Soon | - |
dc.contributor.author | Gerhardt, Rosario A. | - |
dc.contributor.author | Tannenbaum, Rina | - |
dc.date.accessioned | 2024-03-28T16:35:10Z | - |
dc.date.available | 2024-03-28T16:35:10Z | - |
dc.date.created | 2024-03-28 | - |
dc.date.issued | 2014-04 | - |
dc.description.abstract | In the synthesis of the microporous metal-organic framework copper 1,4-benzenedicarboxylate [Cu(BDC)], solvent exchange with methanol prior to recrystallization lowers the desolvation temperature to 160 degrees C and produces more crystalline Cu(BDC). The solution to the crystal structure of Cu(BDC) has been determined by using ab initio quantum molecular calculations and refinement with synchrotron X-ray powder diffraction data. This solution is in the P (1) over bar space group with a = 5.25 angstrom, b = 9.67 angstrom, c = 10.77 angstrom, a = 90.29 degrees, beta = 91.06 degrees, gamma = 92.413 degrees, and V = 546.04 angstrom(3). The Brunauer-Emmett-Teller (BET) surface area was 903 m(2)g(-1) with 777 m(2)g(-1) of micropore surface area. The uptake of CO2 and CH4 up to 20 bar were 5.2 and 2.7 mmolg(-1), respectively. These values are compared to those of 1,3,5-benzenetricarboxylate [Cu-3(BTC)(2), HKUST-1] and used to show that the elevated metal-site density per unit volume is responsible for a proportionally higher uptake on the basis of relative surface areas. The platelike particles with perpendicular pores are promising candidates for mixed-matrix membranes. | - |
dc.identifier.bibliographicCitation | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, v.2014, no.12, pp.2140 - 2145 | - |
dc.identifier.doi | 10.1002/ejic.201301543 | - |
dc.identifier.issn | 1434-1948 | - |
dc.identifier.scopusid | 2-s2.0-84898976587 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/81877 | - |
dc.identifier.wosid | 000334396700015 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Structure Solution from Powder Diffraction of Copper 1,4-Benzenedicarboxylate | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | Metal-organic frameworks | - |
dc.subject.keywordAuthor | Microporous materials | - |
dc.subject.keywordAuthor | Solvent exchange | - |
dc.subject.keywordAuthor | Molecular simulation | - |
dc.subject.keywordAuthor | Structure elucidation | - |
dc.subject.keywordPlus | METAL-ORGANIC FRAMEWORKS | - |
dc.subject.keywordPlus | GAS-OCCLUSION PROPERTIES | - |
dc.subject.keywordPlus | MOLECULAR SIMULATIONS | - |
dc.subject.keywordPlus | MICROPOROUS MATERIALS | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | ADSORPTION | - |
dc.subject.keywordPlus | SEPARATION | - |
dc.subject.keywordPlus | STORAGE | - |
dc.subject.keywordPlus | TRANS-1,4-CYCLOHEXANEDICARBOXYLATE | - |
dc.subject.keywordPlus | CARBOXYLATES | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.