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DC Field | Value | Language |
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dc.citation.endPage | 6579 | - |
dc.citation.number | 22 | - |
dc.citation.startPage | 6575 | - |
dc.citation.title | ELECTROCHIMICA ACTA | - |
dc.citation.volume | 53 | - |
dc.contributor.author | Choi, Nam-Soon | - |
dc.contributor.author | Ryu, Sang-Woog | - |
dc.contributor.author | Park, Jung-Ki | - |
dc.date.accessioned | 2023-12-22T08:37:07Z | - |
dc.date.available | 2023-12-22T08:37:07Z | - |
dc.date.created | 2014-10-01 | - |
dc.date.issued | 2008-09 | - |
dc.description.abstract | The effect of tris(methoxy diethylene glycol) borate (TMDGB) on the coordination structure between ethylene carbonate (EC) solvents with high permittivity and ClO4 - anions has been investigated by using a Fourier transform infrared (FT-IR) spectroscopy. The results of FT-IR analyses manifested that the boron atom of TMDGB anion receptor forms the complex with ClO4 - anions. Even though Lewis acid-base interaction between the TMDGB anion receptor and ClO4 - anions in the electrolyte solution lead to the prominent enhancement of both the dissociation degree of lithium salts and the lithium ion transference number, the ionic conductivity of the EC-based electrolyte solution decreased due to the trap of ClO4 - anions by introducing the TMDGB anion receptor. The electrochemical stability of gel polymer electrolyte based on semi-interpenetrating network (IPN) structure with tris(pentafluoro phenyl) borane (TPFPB) or TMDGB anion receptor was obviously improved. | - |
dc.identifier.bibliographicCitation | ELECTROCHIMICA ACTA, v.53, no.22, pp.6575 - 6579 | - |
dc.identifier.doi | 10.1016/j.electacta.2008.04.070 | - |
dc.identifier.issn | 0013-4686 | - |
dc.identifier.scopusid | 2-s2.0-54249153337 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/6669 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=54249153337 | - |
dc.identifier.wosid | 000258009800040 | - |
dc.language | 영어 | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.title | Effect of tris(methoxy diethylene glycol) borate on ionic conductivity and electrochemical stability of ethylene carbonate-based electrolyte | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | anion receptor | - |
dc.subject.keywordAuthor | TMDGB | - |
dc.subject.keywordAuthor | TPFPB | - |
dc.subject.keywordAuthor | FT-IR | - |
dc.subject.keywordAuthor | lewis acid-base interaction | - |
dc.subject.keywordPlus | LITHIUM BATTERY ELECTROLYTES | - |
dc.subject.keywordPlus | GRAPHITE NEGATIVE ELECTRODE | - |
dc.subject.keywordPlus | ANION RECEPTOR | - |
dc.subject.keywordPlus | THERMAL-STABILITY | - |
dc.subject.keywordPlus | POLYMER ELECTROLYTES | - |
dc.subject.keywordPlus | ANODE | - |
dc.subject.keywordPlus | SALT | - |
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