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- Yoo, Changho
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| DC Field | Value | Language |
|---|---|---|
| dc.citation.number | 9 | - |
| dc.citation.startPage | 1010 | - |
| dc.citation.title | CATALYSTS | - |
| dc.citation.volume | 12 | - |
| dc.contributor.author | Oh, Kyung-Ryul | - |
| dc.contributor.author | Sivan, Sanil E. | - |
| dc.contributor.author | Yoo, Changho | - |
| dc.contributor.author | Hong, Do-Young | - |
| dc.contributor.author | Hwang, Young Kyu | - |
| dc.date.accessioned | 2023-12-21T13:39:27Z | - |
| dc.date.available | 2023-12-21T13:39:27Z | - |
| dc.date.created | 2023-09-05 | - |
| dc.date.issued | 2022-09 | - |
| dc.description.abstract | The synthesis of highly dispersed metal nanoparticles supported on metal-organic frameworks has been widely studied as a means to provide high-performance heterogeneous catalysts. Here, a Ru-nanoparticles-supported MIL-101(Cr) catalyst was prepared via a diamine and oxo-centered trimeric ruthenium cluster ([Ru-3(mu(3)-O)(mu-CH3COO)(6)(H2O)(3)]CH3COO), Ru-3 cluster sequential grafting, followed by alcohol reduction. Ethylenediamine (ED) acted as the linker, coordinating with unsaturated sites on both MIL-101(Cr) and the Ru-3 cluster to produce Ru-3-ED-MIL-101(Cr), after which selective alcohol reduction process provided the Ru/ED-MIL-101(Cr) catalyst. The synthesized Ru/ED-MIL-101(Cr) catalyst contained small, finely dispersed Ru nanoparticles, and the structural integrity of ED-MIL-101(Cr) was maintained. The Ru/ED-MIL-101(Cr) catalyst was tested for the transfer hydrogenation of benzene using isopropanol as the hydrogen source, where it was shown to outperform other Ru-based catalysts. | - |
| dc.identifier.bibliographicCitation | CATALYSTS, v.12, no.9, pp.1010 | - |
| dc.identifier.doi | 10.3390/catal12091010 | - |
| dc.identifier.issn | 2073-4344 | - |
| dc.identifier.scopusid | 2-s2.0-85138634844 | - |
| dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/65385 | - |
| dc.identifier.url | https://www.mdpi.com/2073-4344/12/9/1010 | - |
| dc.identifier.wosid | 000856319000001 | - |
| dc.language | 영어 | - |
| dc.publisher | MDPI | - |
| dc.title | Trimeric Ruthenium Cluster-Derived Ru Nanoparticles Dispersed in MIL-101(Cr) for Catalytic Transfer Hydrogenation | - |
| dc.type | Article | - |
| dc.description.isOpenAccess | TRUE | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.type.docType | Article | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.subject.keywordAuthor | metal-organic framework | - |
| dc.subject.keywordAuthor | trimeric ruthenium cluster | - |
| dc.subject.keywordAuthor | Ru nanoparticle | - |
| dc.subject.keywordAuthor | transfer hydrogenation | - |
| dc.subject.keywordPlus | METAL-ORGANIC-FRAMEWORK | - |
| dc.subject.keywordPlus | CHROMIUM TEREPHTHALATE MIL-101 | - |
| dc.subject.keywordPlus | SELECTIVE HYDROGENATION | - |
| dc.subject.keywordPlus | IN-SITU | - |
| dc.subject.keywordPlus | BENZENE | - |
| dc.subject.keywordPlus | PROGRESS | - |
| dc.subject.keywordPlus | SORPTION | - |
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