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Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 5059 | - |
dc.citation.number | 35 | - |
dc.citation.startPage | 5047 | - |
dc.citation.title | CHEMICAL COMMUNICATIONS | - |
dc.citation.volume | 55 | - |
dc.contributor.author | Yoo, Changho | - |
dc.contributor.author | Dodge, Henry M. | - |
dc.contributor.author | Miller, Alexander J. M. | - |
dc.date.accessioned | 2023-12-21T19:08:46Z | - |
dc.date.available | 2023-12-21T19:08:46Z | - |
dc.date.created | 2023-09-05 | - |
dc.date.issued | 2019-05 | - |
dc.description.abstract | Transition metal complexes that incorporate crown ethers into the supporting ligands have emerged as a powerful class of catalysts capable of cation-tunable reactivity. Cations held in the secondary coordination sphere of a transition metal catalyst can pre-organize or activate substrates, induce local electric fields, adjust structural conformations, or even modify bonding in the primary coordination sphere of the transition metal. This Feature Article begins with a non-comprehensive review of the structural motifs and catalytic applications of crown ether-containing transition metal catalysts, then proceeds to detail the development of catalysts based on "pincer-crown ether" ligands that bridge the primary and secondary coordination spheres. | - |
dc.identifier.bibliographicCitation | CHEMICAL COMMUNICATIONS, v.55, no.35, pp.5047 - 5059 | - |
dc.identifier.doi | 10.1039/c9cc00803a | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.scopusid | 2-s2.0-85065148926 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/65356 | - |
dc.identifier.url | https://pubs.rsc.org/en/content/articlelanding/2019/CC/C9CC00803A | - |
dc.identifier.wosid | 000468624300029 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Cation-controlled catalysis with crown ether-containing transition metal complexes | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Review | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | X-RAY-STRUCTURE | - |
dc.subject.keywordPlus | PHASE-TRANSFER FUNCTION | - |
dc.subject.keywordPlus | C-H OXIDATION | - |
dc.subject.keywordPlus | SUPRAMOLECULAR CHEMISTRY | - |
dc.subject.keywordPlus | METALLACROWN ETHERS | - |
dc.subject.keywordPlus | METHANOL CARBONYLATION | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | KINETIC-DATA | - |
dc.subject.keywordPlus | ION-BINDING | - |
dc.subject.keywordPlus | SALICYLALDIMINE COMPLEXES | - |
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