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dc.citation.number 9 -
dc.citation.title JOURNAL OF CHEMICAL PHYSICS -
dc.citation.volume 122 -
dc.contributor.author Zierhut, M -
dc.contributor.author Noller, B -
dc.contributor.author Schultz, Thomas -
dc.contributor.author Fischer, I -
dc.date.accessioned 2023-12-22T10:39:50Z -
dc.date.available 2023-12-22T10:39:50Z -
dc.date.created 2014-09-19 -
dc.date.issued 2005 -
dc.description.abstract The excited state decay of the hydrocarbon radicals ethyl, C 2H 5; propargyl, C 3H 3; and benzyl, C 7H 7 was investigated by femtosecond time-resolved photoionization. Radicals were generated by flash pyrolysis of n-propyl nitrite, propargyl bromide, and toluene, respectively. It is shown that the 2 2A ′ (3s) Rydberg state of ethyl excited at 250 nm decays with a time constant of 20 fs. No residual signal was observed at longer delay times. For the 3 2B 1 state of propargyl excited at 255 nm a slower decay with a time constant 50±10 fs was determined. The 4 2B 2 state of benzyl excited at 255 nm decays within 150±30 fs. -
dc.identifier.bibliographicCitation JOURNAL OF CHEMICAL PHYSICS, v.122, no.9 -
dc.identifier.doi 10.1063/1.1857475 -
dc.identifier.issn 0021-9606 -
dc.identifier.scopusid 2-s2.0-22944445465 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/6265 -
dc.identifier.url http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=22944445465 -
dc.identifier.wosid 000227483300023 -
dc.language 영어 -
dc.publisher AMER INST PHYSICS -
dc.title Excited-state decay of hydrocarbon radicals, investigated by femtosecond time-resolved photoionization: Ethyl, propargyl, and benzyl -
dc.type Article -
dc.description.journalRegisteredClass scopus -

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