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- Schultz, Thomas
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| DC Field | Value | Language |
|---|---|---|
| dc.citation.endPage | 1786 | - |
| dc.citation.number | 6 | - |
| dc.citation.startPage | 1782 | - |
| dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
| dc.citation.volume | 127 | - |
| dc.contributor.author | Samoylova, E. | - |
| dc.contributor.author | Lippert, H. | - |
| dc.contributor.author | Ullrich, S. | - |
| dc.contributor.author | Hertel, I.V. | - |
| dc.contributor.author | Radloff, W. | - |
| dc.contributor.author | Schultz, Thomas | - |
| dc.date.accessioned | 2023-12-22T10:38:37Z | - |
| dc.date.available | 2023-12-22T10:38:37Z | - |
| dc.date.created | 2014-09-19 | - |
| dc.date.issued | 2005-02 | - |
| dc.description.abstract | The excited-state dynamics of adenine and thymine dimers and the adenine-thymine base pair were investigated by femtosecond pump-probe ionization spectroscopy with excitation wavelengths of 250-272 nm. The base pairs showed a characteristic ultrafast decay of the initially excited ππ* state to an nπ* state (lifetime τππ• ≈ 100 fs) followed by a slower decay of the latter with τnπ* ≈ 0.9 ps for (adenine)2, τnπ* = 6-9 ps for (thymine)2, and τnπ* ≈ 2.4 ps for the adenine-thymine base pair. In the adenine dimer, a competing decay of the ππ* state via the πσ* state greatly suppressed the nπ* state signals. Similarities of the excited-state decay parameters in the isolated bases and the base pairs suggest an intramonomer relaxation mechanism in the base pairs. | - |
| dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.127, no.6, pp.1782 - 1786 | - |
| dc.identifier.doi | 10.1021/ja044369q | - |
| dc.identifier.issn | 0002-7863 | - |
| dc.identifier.scopusid | 2-s2.0-13644263208 | - |
| dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/6264 | - |
| dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=13644263208 | - |
| dc.identifier.wosid | 000226951800049 | - |
| dc.language | 영어 | - |
| dc.publisher | AMER CHEMICAL SOC | - |
| dc.title | Dynamics of photoinduced processes in adenine and thymine base pairs | - |
| dc.type | Article | - |
| dc.description.journalRegisteredClass | scopus | - |
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