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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 1625 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | 1613 | - |
dc.citation.title | ACS ENERGY LETTERS | - |
dc.citation.volume | 8 | - |
dc.contributor.author | Xiong, Peixun | - |
dc.contributor.author | Kang, Yingbo | - |
dc.contributor.author | Yao, Nan | - |
dc.contributor.author | Chen, Xiang | - |
dc.contributor.author | Mao, Haiyan | - |
dc.contributor.author | Jang, Woo-Sung | - |
dc.contributor.author | Halat, David M. | - |
dc.contributor.author | Fu, Zhong-Heng | - |
dc.contributor.author | Jung, Min-Hyoung | - |
dc.contributor.author | Jeong, Hu Young | - |
dc.contributor.author | Kim, Young-Min | - |
dc.contributor.author | Reimer, Jeffrey A. | - |
dc.contributor.author | Zhang, Qiang | - |
dc.contributor.author | Park, Ho Seok | - |
dc.date.accessioned | 2023-12-21T12:47:55Z | - |
dc.date.available | 2023-12-21T12:47:55Z | - |
dc.date.created | 2023-03-28 | - |
dc.date.issued | 2023-03 | - |
dc.description.abstract | Hydrogen evolution, corrosion, and dendrite for-mation in the Zn anodes limit their practical applications in aqueous Zn metal batteries. Herein, we propose an interfacial chemistry regulation strategy that uses hybrid electrolytes of water and a polar aprotic N,N-dimethylformamide to modify the Zn2+- solvation structure and in situ form a robust and Zn2+-conducting Zn5(CO3)2(OH)6 solid electrolyte interphase (SEI) on the Zn surface to achieve stable and dendrite-free Zn plating/stripping over a wide temperature range. As confirmed by 67Zn nuclear magnetic resonance relaxometry, electrochemical characteriza-tions, and molecular dynamics simulation, the electrochemically and thermally stable Zn5(OH)6(CO3)2-contained SEI achieved a high ionic conductivity of 0.04 to 1.27 mS cm-1 from -30 to 70 degrees C and a thermally activated fast Zn2+ migration through the [010] plane. Consequently, extremely stable Zn-ion hybrid capacitors in hybrid electrolytes are demonstrated with high capacity retentions and Coulombic efficiencies over 14,000, 10,000, and 600 cycles at 25, -20, and 70 degrees C, respectively. | - |
dc.identifier.bibliographicCitation | ACS ENERGY LETTERS, v.8, no.3, pp.1613 - 1625 | - |
dc.identifier.doi | 10.1021/acsenergylett.3c00154 | - |
dc.identifier.issn | 2380-8195 | - |
dc.identifier.scopusid | 2-s2.0-85149125687 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/62449 | - |
dc.identifier.wosid | 000939406800001 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Zn-Ion Transporting, In Situ Formed Robust Solid Electrolyte Interphase for Stable Zinc Metal Anodes over a Wide Temperature Range | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Electrochemistry; Energy & Fuels; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science | - |
dc.type.docType | Article; Early Access | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | LONG-LIFE | - |
dc.subject.keywordPlus | BATTERY | - |
dc.subject.keywordPlus | SOLVENT | - |
dc.subject.keywordPlus | ACETATE | - |
dc.subject.keywordPlus | IMPACT | - |
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