Solvated electrons at the water-air interface: surface versus bulk signal in low kinetic energy photoelectron spectroscopy
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- Solvated electrons at the water-air interface: surface versus bulk signal in low kinetic energy photoelectron spectroscopy
- Buchner, Franziska; Schultz, Thomas; Luebcke, Andrea
- MOLECULAR-DYNAMICS SIMULATION; PUMP-PROBE SPECTROSCOPY; HYDRATED-ELECTRON; COMPUTER-SIMULATION; CLUSTER ANIONS; LIQUID WATER; IODIDE; ABSORPTION; CAVITY; OCCUPY
- Issue Date
- ROYAL SOC CHEMISTRY
- PHYSICAL CHEMISTRY CHEMICAL PHYSICS, v.14, no.16, pp.5837 - 5842
- Time-resolved photoelectron spectroscopy at low kinetic energies (less than or similar to 5 eV) is applied to dilute iodide solutions with different surface and bulk contributions. The results indicate a pronounced surface sensitivity. Signals assigned to solvated electrons near the liquid surface decay rapidly on a sub-ps timescale. In contrast to the literature, a long-lived surface solvated electron at 1.6 eV binding energy is not observed.
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