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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 3379 | - |
dc.citation.number | 8 | - |
dc.citation.startPage | 3376 | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 141 | - |
dc.contributor.author | Mizoguchi, Hiroshi | - |
dc.contributor.author | Park, Sang-Won | - |
dc.contributor.author | Kishida, Kazuhisa | - |
dc.contributor.author | Kitano, Masaaki | - |
dc.contributor.author | Kim, Junghwan | - |
dc.contributor.author | Sasase, Masato | - |
dc.contributor.author | Honda, Takashi | - |
dc.contributor.author | Ikeda, Kazutaka | - |
dc.contributor.author | Otomo, Toshiya | - |
dc.contributor.author | Hosono, Hideo | - |
dc.date.accessioned | 2023-12-21T19:37:02Z | - |
dc.date.available | 2023-12-21T19:37:02Z | - |
dc.date.created | 2023-01-16 | - |
dc.date.issued | 2019-02 | - |
dc.description.abstract | LnNiSi (Ln = La-Nd) comprising a three-dimensional NiSi framework has electrons in the crystallographic cavity space. In the temperature region 473-773 K, it accepts the insertion/de-insertion of hydrogen topotactically without a change in unitcell volume. The insertion of hydrogens into the cavity space is accompanied by a redox reaction with the orbitals of atoms constituting the cavity wall. Having small work functions, such intermetallic electrides exhibit metallic electrical and magnetic properties. Owing to a high electron-donating power and reversible exchange between hydrogen and the electrons, Ru5wt%-loaded LaNiSi powder worked as an efficient catalyst for ammonia synthesis under ambient pressure. | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.141, no.8, pp.3376 - 3379 | - |
dc.identifier.doi | 10.1021/jacs.8b12784 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.scopusid | 2-s2.0-85061893190 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/62095 | - |
dc.identifier.wosid | 000460200100009 | - |
dc.language | 영어 | - |
dc.publisher | American Chemical Society | - |
dc.title | Zeolitic Intermetallics: LnNiSi (Ln = La-Nd) | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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