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Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)

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Manganese metallamacrocycles with various coordination solvents

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Title
Manganese metallamacrocycles with various coordination solvents
Author
Song, JMoon, DLah, Myoung Soo
Keywords
Hexanuclear metallamacrocycle; Macrocyclic ring; Manganese metallamacrocycle; N-Acylsalicylhydrazide; Self-assembly
Issue Date
200205
Publisher
KOREAN CHEMICAL SOC
Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.23, no.5, pp.708 - 714
Abstract
The hexanuclear metallamacrocycles were observed repeatedly in various conditions including the presence of several different tricationic metal ions in the macrocyclic ring system and of the linear alkyl chains at the acyl site of N-acylsalicylhydrazide ligand, which contrasts to the formation of the decanuclear metallamacrocycle with bulkier side chains such as phenyl group at the acyl site of the ligand. We synthesized a series of metallamacrocycles in various solvents to find the relationship between the solvents and the nuclearity of the metallamacrocycles. Whether the solvents are sterically more demanding or not, the complexes formed kept the hexanuclear metallamacrocycle system.
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ISSN
0253-2964
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