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나명수

Lah, Myoung Soo
Frontier Energy Storage Material Lab.
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Manganese metallamacrocycles with various coordination solvents

Author(s)
Song, JMoon, DLah, Myoung Soo
Issued Date
2002-05
URI
https://scholarworks.unist.ac.kr/handle/201301/6094
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0037141145
Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.23, no.5, pp.708 - 714
Abstract
The hexanuclear metallamacrocycles were observed repeatedly in various conditions including the presence of several different tricationic metal ions in the macrocyclic ring system and of the linear alkyl chains at the acyl site of N-acylsalicylhydrazide ligand, which contrasts to the formation of the decanuclear metallamacrocycle with bulkier side chains such as phenyl group at the acyl site of the ligand. We synthesized a series of metallamacrocycles in various solvents to find the relationship between the solvents and the nuclearity of the metallamacrocycles. Whether the solvents are sterically more demanding or not, the complexes formed kept the hexanuclear metallamacrocycle system.
Publisher
KOREAN CHEMICAL SOC
ISSN
0253-2964

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